ArticleAdvanced materials (Deerfield Beach, Fla.)2021
Interfacial Covalent Bonds Regulated Electron-Deficient 2D Black Phosphorus for Electrocatalytic Oxygen Reactions.
Article in Advanced materials (Deerfield Beach, Fla.), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Gradient Zinc-Doping Strategy Combined With Tumor Metabolic Interference for Effective Catalytic Immunotherapy.Advanced healthcare materials · 2026Article
- Tailoring Cobalt-Based Nanomaterials through Doping and Vacancy Engineering for Advanced Hydrogen Evolution Reaction (HER) and Oxygen Evolution Reaction (OER) Electrolysis.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
- Boosting 2D Black Phosphorus Ambient Stability: Noncovalent Functionalization Using Viologen Molecules.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Exploration of metal-free 2D electrocatalysts toward the oxygen electroreduction.Exploration (Beijing, China) · 2024Review
- Design Principles and Mechanistic Understandings of Non-Noble-Metal Bifunctional Electrocatalysts for Zinc-Air Batteries.Nano-micro letters · 2024Review
- Covalently Bonded Ni Sites in Black Phosphorene with Electron Redistribution for Efficient Metal-Lightweighted Water Electrolysis.Nano-micro letters · 2024Article
- Recent advances of bifunctional catalysts for zinc air batteries with stability considerations: from selecting materials to reconstruction.Nanoscale advances · 2023Review
- Atomically Dispersed Pentacoordinated-Zirconium Catalyst with Axial Oxygen Ligand for Oxygen Reduction Reaction.Angewandte Chemie (International ed. in English) · 2022Article
- Material design and surface chemistry for advanced rechargeable zinc-air batteries.Chemical science · 2022Review
- A Kinetically Superior Rechargeable Zinc-Air Battery Derived from Efficient Electroseparation of Zinc, Lead, and Copper in Concentrated Solutions.ChemSusChem · 2022Article
- Degradation and regeneration of Fe-NChemical science · 2021Article
- Interfacial Covalent Bonds Regulated Electron-Deficient 2D Black Phosphorus for Electrocatalytic Oxygen Reactions.Advanced materials (Deerfield Beach, Fla.) · 2021Article
Corrections and comments
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Authors and funding
15 authors.
Funding
Abstract
Developing resource-abundant and sustainable metal-free bifunctional oxygen electrocatalysts is essential for the practical application of zinc-air batteries (ZABs). 2D black phosphorus (BP) with fully exposed atoms and active lone pair electrons can be promising for oxygen electrocatalysts, which, however, suffers from low catalytic activity and poor electrochemical stability. Herein, guided by density functional theory (DFT) calculations, an efficient metal-free electrocatalyst is demonstrated via covalently bonding BP nanosheets with graphitic carbon nitride (denoted BP-CN-c). The polarized PN covalent bonds in BP-CN-c can efficiently regulate the electron transfer from BP to graphitic carbon nitride and significantly promote the OOH* adsorption on phosphorus atoms. Impressively, the oxygen evolution reaction performance of BP-CN-c (overpotential of 350 mV at 10 mA cm
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