Evidence map›Paper›PMID 33938629›Full record

ArticleAngewandte Chemie (International ed. in English)2021

Conformational Control of Chemical Reactivity for Surface-Confined Ru-Porphyrins.

Peter Knecht, Joachim Reichert, Peter S Deimel, Peter Feulner, Felix Haag, Francesco Allegretti, Manuela Garnica, Martin Schwarz, Willi Auwärter, Paul T P Ryan and 5 more

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. N-Heterocyclic Carbenes: Molecular Porters of Surface Mounted Ru-Porphyrins.Angewandte Chemie (International ed. in English) · 2022
    Article
  5. Conformational Control of Chemical Reactivity for Surface-Confined Ru-Porphyrins.Angewandte Chemie (International ed. in English) · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

15 authors.

Peter KnechtPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.ORCID http://orcid.org/0000-0002-9506-9304
Joachim ReichertPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.ORCID http://orcid.org/0000-0002-8843-3972
Peter S DeimelPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.
Peter FeulnerPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.
Felix HaagPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.
Francesco AllegrettiPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.ORCID http://orcid.org/0000-0001-6141-7166
Manuela GarnicaPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.ORCID http://orcid.org/0000-0002-7861-9490
Martin SchwarzPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.
Willi AuwärterPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.ORCID http://orcid.org/0000-0001-9452-4662
Paul T P RyanDiamond Light Source, Didcot, OX11 0DE, UK.
Tien-Lin LeeDiamond Light Source, Didcot, OX11 0DE, UK.
David A DuncanDiamond Light Source, Didcot, OX11 0DE, UK.ORCID http://orcid.org/0000-0002-0827-2022
Ari Paavo SeitsonenDépartement de Chimie, Ecole Normale Supérieure, 24 rue Lhomond, 75005, Paris, France.ORCID http://orcid.org/0000-0003-4331-0650
Johannes V BarthPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.ORCID http://orcid.org/0000-0002-6270-2150
Anthoula C PapageorgiouPhysics Department E20, Technical University of Munich, James Franck Straße 1, 85748, Garching, Germany.ORCID http://orcid.org/0000-0003-1054-0097

Funding

Deutsche Forschungsgemeinschaft EXC 2089: e-conversionDeutsche Forschungsgemeinschaft Heisenberg professorshipDeutsche Forschungsgemeinschaft International Graduate School of Science and Engineering (IGSSE) at TUMDeutsche Forschungsgemeinschaft Subproject of Priority Programme SPP 1928Diamond Light Source SI24320-1Engineering and Physical Sciences Research Council EP/L015277/1European Research Council 615233H2020 Marie Skłodowska-Curie Actions 658070
6 · The paper itself

Abstract

We assess the crucial role of tetrapyrrole flexibility in the CO ligation to distinct Ru-porphyrins supported on an atomistically well-defined Ag(111) substrate. Our systematic real-space visualisation and manipulation experiments with scanning tunnelling microscopy directly probe the ligation, while bond-resolving atomic force microscopy and X-ray standing-wave measurements characterise the geometry, X-ray and ultraviolet photoelectron spectroscopy the electronic structure, and temperature-programmed desorption the binding strength. Density-functional-theory calculations provide additional insight into the functional interface. We unambiguously demonstrate that the substituents regulate the interfacial conformational adaptability, either promoting or obstructing the uptake of axial CO adducts.

Indexed as

ab-initio calculationsCO ligandsmetalloporphyrinsscanning probe microscopyX-ray spectroscopy

Identifiers

PMID33938629
PMCPMC8362151

What OpenQuestion holds

Textmetadata
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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.