ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
Electrochemical Synthesis of Organic Polysulfides from Disulfides by Sulfur Insertion from S
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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2 citing papers in PubMed, 7 citations in OpenAlex.
- Sulfur-Rich Polymers From Elemental Sulfur: Sustainable Pathways and Emerging Applications in Sustainable Materials (2021-2025).Chemistry, an Asian journal · 2026Review
- Electrochemical Synthesis of Organic Polysulfides from Disulfides by Sulfur Insertion from SChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
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2 authors at 1 institution in 1 country.
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Abstract
An electrochemical synthesis of organic polysulfides through sulfur insertion from elemental sulfur to disulfides or thiols is introduced. The highly economic, low-sensitive and low-priced reaction gives a mixture of polysulfides, whose distribution can be influenced by the addition of different amounts of carbon disulfide as co-solvent. To describe the variable distribution function of the polysulfides, a novel parameter, the "absorbance average sulfur amount in polysulfides" (SAP) was introduced and defined on the basis of the "number average molar mass" used in polymer chemistry. Various organic polysulfides were synthesized with variable volume fractions of carbon disulfide, and the yield of each polysulfide was determined by quantitative
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