ArticleScience advances2021
Direct observation of hyperpolarization breaking through the spin diffusion barrier.
Article in Science advances, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
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Who cites it
22 citing papers in PubMed.
- Symmetry-based pulsed DNP and EPR sequences.Science advances · 2026Article
- Quantum coherence enhancement through control of metal-ligand covalency: modulating spin-orbit coupling in isostructural molecular qubits.Chemical science · 2026Article
- Characterization of strongly hyperfine-split protons by DNP.Physical chemistry chemical physics : PCCP · 2026Article
- Coherent Control over Nuclear Hyperpolarization Using an Optically Initializable Chromophore-Radical System.Journal of the American Chemical Society · 2025Article
- Nanoscale engineering and dynamic stabilization of mesoscopic spin textures.Science advances · 2025Article
- RIDME Spectroscopy: New Topics Beyond the Determination of Electron Spin-Spin Distances.The journal of physical chemistry letters · 2025Review
- Indirect Detection of the Protons in and around Biradicals and their Mechanistic Role in MAS-DNP.The journal of physical chemistry letters · 2025Article
- Two-electron two-nucleus effective Hamiltonian and the spin diffusion barrier.Science advances · 2025Article
- ih-RIDME: a pulse EPR experiment to probe the heterogeneous nuclear environment.Magnetic resonance (Gottingen, Germany) · 2025Article
- Hypershifted spin spectroscopy with dynamic nuclear polarization at 1.4 K.Science advances · 2024Article
- BoostingScience advances · 2024Article
- Controlled synthesis and characterization of porous silicon nanoparticles for dynamic nuclear polarization.Nanoscale · 2024Article
- Relaxation enhancement by microwave irradiation may limit dynamic nuclear polarization.Physical chemistry chemical physics : PCCP · 2024Article
- Role of Protons in and around Strongly Coupled Nitroxide Biradicals for Cross-Effect Dynamic Nuclear Polarization.The journal of physical chemistry letters · 2024Article
- Singlet fission as a polarized spin generator for dynamic nuclear polarization.Nature communications · 2023Article
- Spin Hyperpolarization in Modern Magnetic Resonance.Chemical reviews · 2023Review
- Modelling and correcting the impact of RF pulses for continuous monitoring of hyperpolarized NMR.Magnetic resonance (Gottingen, Germany) · 2023Article
- Observing Nearby Nuclei on Paramagnetic Trityls and MOFs via DNP and Electron Decoupling.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Observation of a four-spin solid effect.The Journal of chemical physics · 2022Article
- Reverse dynamic nuclear polarisation for indirect detection of nuclear spins close to unpaired electrons.Magnetic resonance (Gottingen, Germany) · 2022Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
Dynamic nuclear polarization (DNP) is a widely used tool for overcoming the low intrinsic sensitivity of nuclear magnetic resonance spectroscopy and imaging. Its practical applicability is typically bounded, however, by the so-called "spin diffusion barrier," which relates to the poor efficiency of polarization transfer from highly polarized nuclei close to paramagnetic centers to bulk nuclei. A quantitative assessment of this barrier has been hindered so far by the lack of general methods for studying nuclear polarization flow in the vicinity of paramagnetic centers. Here, we fill this gap and introduce a general set of experiments based on microwave gating that are readily implemented. We demonstrate the versatility of our approach in experiments conducted between 1.2 and 4.2 K in static mode and at 100 K under magic angle spinning (MAS)-conditions typical for dissolution DNP and MAS-DNP-and directly observe the marked dependence of polarization flow on temperature.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.