ArticleJournal of the American Chemical Society2021
Spin Filtering in Supramolecular Polymers Assembled from Achiral Monomers Mediated by Chiral Solvents.
Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 41 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
41 citing papers in PubMed.
- An X‑Shaped Chiral Non‑Fullerene n-Type Semiconductor: Application in Perovskite Solar Cells and Chirality‑Induced Spin Selectivity.Angewandte Chemie (International ed. in English) · 2026Article
- Chiral Bifacial Indacenodithiophene-Based Hole-Transport Materials With Chirality-Induced Spin Selectivity: Chirality-Spin Polarity Correspondence and Perovskite Passivation.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Bifacial ladder polymers enabled by chirality-assisted synthesis that exhibit self-assembly and chirality-induced spin selectivity.Nature communications · 2026Article
- Highly Chiral MoSSmall science · 2026Article
- Chirality induced long-range spin-selective transport in helical 3D metal-organic frameworks.Chemical science · 2026Article
- Close-Shell and Biradical Enantiomers for Probing the Chiral-Induced Spin Selectivity Effect.The journal of physical chemistry letters · 2026Article
- Chirality-Induced Spin Selectivity in Two-Dimensional Self-Assembled Molecular Networks.Journal of the American Chemical Society · 2025Article
- Chiral two-dimensional conjugated metal-organic frameworks with high spin polarization.Nature communications · 2025Article
- Chirality-Induced Spin-Orbit Coupling and Spin Selectivity.The journal of physical chemistry. A · 2025Article
- Chirality-Induced Spin Selectivity: A Minimal Model.The journal of physical chemistry letters · 2025Article
- Supramolecular chiral inversion and regulation of phenylalanine-based organogels in low-polarity achiral solvents.Communications chemistry · 2025Article
- Too Fast for Spin Flipping: Absence of Chirality-Induced Spin Selectivity in Coherent Electron Transport through Single-Molecule Junctions.Journal of the American Chemical Society · 2025Article
- Article
- Article
- Homochiral Carboxylate-Anchored Truxene Tripods: Design, Synthesis, and Monolayer Formation on Ag(111).Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Amplifying and Reversing the Chiral Bias in Asymmetric Photo-Polymerization Reaction.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Secondary nucleation guided noncovalent synthesis of dendritic homochiral superstructures via growth on and from surface.Nature communications · 2024Article
- The chirality-induced spin selectivity effect in asymmetric spin transport: from solution to device applications.Chemical science · 2024Review
- Engineering spin-dependent catalysts: chiral covalent organic frameworks with tunable electroactivity for electrochemical oxygen evolution.National science review · 2024Article
- A chemical perspective on the chiral induced spin selectivity effect.National science review · 2024Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In past studies, spin selective transport was observed in polymers and supramolecular structures that are based on homochiral building blocks possessing stereocenters. Here we address the question to what extent chiral building blocks are required for observing the chiral induced spin selectivity (CISS) effect. We demonstrate the CISS effect in supramolecular polymers exclusively containing achiral monomers, where the supramolecular chirality was induced by chiral solvents that were removed from the fibers before measuring. Spin-selective transport was observed for electrons transmitted perpendicular to the fibers' long axis. The spin polarization correlates with the intensity of the CD spectra of the polymers, indicating that the effect is nonlocal. It is found that the spin polarization increases with the samples' thickness and the thickness dependence is the result of at least two mechanisms: the first is the CISS effect, and the second reduces the spin polarization due to scattering. Temperature dependence studies provide the first support for theoretical work that suggested that phonons may contribute to the spin polarization.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.