ArticleMolecules (Basel, Switzerland)2021
Using Room Temperature Phosphorescence of Gold(I) Complexes for PAHs Sensing.
Article in Molecules (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Harnessing Triplets of TIPS-Anthracene-Based Au(I) Complexes for Photoinduced Electron Transfer and Room-Temperature Phosphorescence.Inorganic chemistry · 2026Article
- Unlocking Arene Phosphorescence in Bismuth-Organic Materials.Inorganic chemistry · 2024Article
- Heterometallic Au(I)-Cu(I) Clusters: Luminescence Studies andInorganic chemistry · 2023Article
- Intra- vs Intermolecular Aurophilic Contacts in Dinuclear Gold(I) Compounds: Impact on the Population of the Triplet Excited State.Inorganic chemistry · 2022Article
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Authors and funding
8 authors.
Funding
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Abstract
The synthesis of two new phosphane-gold(I)-napthalimide complexes has been performed and characterized. The compounds present luminescent properties with denoted room temperature phosphorescence (RTP) induced by the proximity of the gold(I) heavy atom that favors intersystem crossing and triplet state population. The emissive properties of the compounds together with the planarity of their chromophore were used to investigate their potential as hosts in the molecular recognition of different polycyclic aromatic hydrocarbons (PAHs). Naphthalene, anthracene, phenanthrene, and pyrene were chosen to evaluate how the size and electronic properties can affect the host:guest interactions. Stronger affinity has been detected through emission titrations for the PAHs with extended aromaticity (anthracene and pyrene) and the results have been supported by DFT calculation studies.
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