ArticleNanomaterials (Basel, Switzerland)2021
Ultrahigh-Pressure Preparation and Catalytic Activity of MOF-Derived Cu Nanoparticles.
Article in Nanomaterials (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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6 citing papers in PubMed, 16 citations in OpenAlex.
- Modification of Biochar Catalyst Using Copper for Enhanced Catalytic Oxidation of VOCs.Toxics · 2025Article
- Synthesis of Electrocatalytic Tungsten Carbide Nanoparticles by High-Pressure and High-Temperature Treatment of Organotungsten Compounds.Nanomaterials (Basel, Switzerland) · 2025Article
- Article
- Research progress on MOFs and their derivatives as promising and efficient electrode materials for electrocatalytic hydrogen production from water.RSC advances · 2023Review
- Ultrahigh pressure-induced modification of morphology and performance of MOF-derived Cu@C electrocatalysts.Nanoscale advances · 2023Article
- MOF-Derived Cu@N-C Catalyst for 1,3-Dipolar Cycloaddition Reaction.Nanomaterials (Basel, Switzerland) · 2022Article
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8 authors at 1 institution in 1 country.
Funding
Abstract
A metal-organic framework (MOF) consisting of Cu-benzenetricarboxylic acid was processed under ultrahigh pressure (5 GPa) and at temperature of up to 500 °C. The products were characterized with TEM, FTIR, and XAFS. The decomposition of the MOF started at 200 °C at 5 GPa. This temperature was much lower than that in the vacuum. Single-nanometer Cu nanoparticles were obtained in carbon matrix, which was significantly smaller than the Cu particles prepared at ambient pressure. The catalytic activity for Huisgen cycloaddition was examined, and the sample processed at 5 GPa showed a much improved performance compared with that of the MOF-derived Cu nanoparticles prepared without high pressure.
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