ArticleInternational journal of molecular sciences2021
Bis(trifluoromethylsulfonyl)imide Ionic Liquids Applied for Fine-Tuning the Cure Characteristics and Performance of Natural Rubber Composites.
Article in International journal of molecular sciences, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed, 28 citations in OpenAlex.
- Elastomeric Biocomposites of Natural Rubber Containing Biosynthesized Zinc Oxide.International journal of molecular sciences · 2025Article
- Alfalfa/Lucerne (Polymers · 2024Article
- Multifunctional Applications of Ionic Liquids in Polymer Materials: A Brief Review.Molecules (Basel, Switzerland) · 2023Review
- Potential Utilization of Ground Eggshells as a Biofiller for Natural Rubber Biocomposites.Materials (Basel, Switzerland) · 2023Article
- The Potential Application of Starch and Walnut Shells as Biofillers for Natural Rubber (NR) Composites.International journal of molecular sciences · 2022Article
- Study on Increasing the Binding Amount of Rubber and Reinforcing Filler by Adding Aromatic Solvent Oil.Polymers · 2022Article
- Bromide and Chloride Ionic Liquids Applied to Enhance the Vulcanization and Performance of Natural Rubber Biocomposites Filled with Nanosized Silica.Nanomaterials (Basel, Switzerland) · 2022Article
- The Physical Chemistry and Chemical Physics (PCCP) Section of theInternational journal of molecular sciences · 2021Article
- Raw natural rubber latex-based bio-adhesive for the production of particleboard: formulation and optimization of process parameters.RSC advances · 2021Article
- Influence of Fillers and Ionic Liquids on the Crosslinking and Performance of Natural Rubber Biocomposites.Polymers · 2021Article
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The goal of this work was to apply ionic liquids (ILs) with bis(trifluoromethylsulfonyl)imide anion (TFSI) for fine-tuning the cure characteristics and physico-chemical properties of elastomer composites based on a biodegradable natural rubber (NR) matrix. ILs with TFSI anion and different cations, such as alkylpyrrolidinium, alkylammonium, and alkylsulfonium cations, were applied to increase the efficiency of sulfur vulcanization and to improve the performance of NR composites. Thus, the influence of ILs on the vulcanization of NR compounds, as well as crosslink density and physical properties of NR vulcanizates, including tensile properties, thermal stability, and resistance to thermo-oxidative aging was explored. The activity of ILs seems to be strongly dependent on their cation. Pyrrolidinium and ammonium ILs effectively supported the vulcanization, reducing the optimal vulcanization time and temperature of NR compounds and increasing the crosslink density of the vulcanizates. Consequently, vulcanizates with these ILs exhibited higher tensile strength than the benchmark without IL. On the other hand, sulfonium ILs reduced the torque increment owing to the lower crosslinking degree of elastomer but significantly improved the resistance of NR composites to thermo-oxidation. Thus, TFSI ILs can be used to align the curing behavior and performance of NR composites for particular applications.
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