Evidence map›Paper›PMID 33905140›Full record

ArticleAngewandte Chemie (International ed. in English)2021

Isoreticular Crystallization of Highly Porous Cubic Covalent Organic Cage Compounds*.

Svetlana Ivanova, Eva Köster, Julian J Holstein, Niklas Keller, Guido H Clever, Thomas Bein, Florian Beuerle

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.

0numbers the graph read from it
0cells of the map it votes in
11citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

11 citing papers in PubMed.

  1. Ion-Permselective Porous Organic Cage Membranes.Angewandte Chemie (International ed. in English) · 2026
    Review
  2. Article
  3. Article
  4. Article
  5. A Water-Stable Boronate Ester Cage.Journal of the American Chemical Society · 2024
    Article
  6. COChemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Article
  7. Review
  8. Article
  9. Article
  10. Article
  11. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Svetlana IvanovaJulius-Maximilians-Universität Würzburg, Institut für Organische Chemie, Am Hubland, 97074, Würzburg, Germany.ORCID http://orcid.org/0000-0002-4999-8401
Eva KösterJulius-Maximilians-Universität Würzburg, Institut für Organische Chemie, Am Hubland, 97074, Würzburg, Germany.
Julian J HolsteinTechnische Universität Dortmund, Fakultät für Chemie und Chemische Biologie, Otto-Hahn-Strasse 6, 44227, Dortmund, Germany.ORCID http://orcid.org/0000-0002-8385-7805
Niklas KellerLudwig-Maximilians-Universität München, Department of Chemistry & Center for NanoScience (CeNS), Butenandtstrasse 5-13, 81377, München, Germany.ORCID http://orcid.org/0000-0003-1581-072X
Guido H CleverTechnische Universität Dortmund, Fakultät für Chemie und Chemische Biologie, Otto-Hahn-Strasse 6, 44227, Dortmund, Germany.ORCID http://orcid.org/0000-0001-8458-3060
Thomas BeinLudwig-Maximilians-Universität München, Department of Chemistry & Center for NanoScience (CeNS), Butenandtstrasse 5-13, 81377, München, Germany.ORCID http://orcid.org/0000-0001-7248-5906
Florian BeuerleJulius-Maximilians-Universität Würzburg, Institut für Organische Chemie, Am Hubland, 97074, Würzburg, Germany.ORCID http://orcid.org/0000-0001-7239-8327

Funding

Bayerisches Staatsministerium für Wissenschaft, Forschung und Kunst Solar Technologies Go HybridDeutsche Forschungsgemeinschaft BE4808/2-1
6 · The paper itself

Abstract

Modular frameworks featuring well-defined pore structures in microscale domains establish tailor-made porous materials. For open molecular solids however, maintaining long-range order after desolvation is inherently challenging, since packing is usually governed by only a few supramolecular interactions. Here we report on two series of nanocubes obtained by co-condensation of two different hexahydroxy tribenzotriquinacenes (TBTQs) and benzene-1,4-diboronic acids (BDBAs) with varying linear alkyl chains in 2,5-position. n-Butyl groups at the apical position of the TBTQ vertices yielded soluble model compounds, which were analyzed by mass spectrometry and NMR spectroscopy. In contrast, methyl-substituted cages spontaneously crystallized as isostructural and highly porous solids with BET surface areas and pore volumes of up to 3426 m

Indexed as

boronate esterscage compoundsdynamic covalent chemistryporous materialsstructure elucidation

Identifiers

PMID33905140
PMCPMC8362030

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.