ArticleAngewandte Chemie (International ed. in English)2021
Transition Metal Catalyst-Free, Base-Promoted 1,2-Additions of Polyfluorophenylboronates to Aldehydes and Ketones.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed.
- Transient π-coordination enables nucleophilic borylation of simple arenes.Chemical science · 2026Article
- Catalytic 1,2-Migratory Insertion in a Bismuth Redox Platform: Reductive Arylation of Aldehydes.Angewandte Chemie (International ed. in English) · 2025Article
- Applications of Transition Metal-CatalyzedChemical reviews · 2024Review
- Solvent- and Catalyst-Free Synthesis ofMolecules (Basel, Switzerland) · 2024Article
- Visible-light-induced selective defluoroalkylations of polyfluoroarenes with alcohols.Chemical science · 2023Article
- Transition Metal Catalyst-Free, Base-Promoted 1,2-Additions of Polyfluorophenylboronates to Aldehydes and Ketones.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
A novel protocol for the transition metal-free 1,2-addition of polyfluoroaryl boronate esters to aldehydes and ketones is reported, which provides secondary alcohols, tertiary alcohols, and ketones. Control experiments and DFT calculations indicate that both the ortho-F substituents on the polyfluorophenyl boronates and the counterion K
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Registered trials
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