Evidence map›Paper›PMID 33869663›Full record

ArticleStructural dynamics (Melville, N.Y.)2021

Element-specific investigations of ultrafast dynamics in photoexcited Cu

Christian Rein, Jens Uhlig, David Carrasco-Busturia, Khadijeh Khalili, Anders S Gertsen, Asbjørn Moltke, Xiaoyi Zhang, Tetsuo Katayama, Juan Maria García Lastra, Martin Meedom Nielsen and 3 more

Open access · goldAbstract read
In one paragraph

Article in Structural dynamics (Melville, N.Y.), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
0.1field-weighted citation impact, top 59% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 3 citations in OpenAlex.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors at 1 institution in 4 countries.

Christian ReinDepartment of Energy Conversion and Storage, Technical University of Denmark, Fysikvej, 2800 Kgs., Lyngby, Denmark.
Jens UhligNanoLund and Chemical Physics, Lund University, Box 124, 22100 Lund, Sweden.ORCID https://orcid.org/0000-0002-0528-0422
David Carrasco-BusturiaDepartment of Energy Conversion and Storage, Technical University of Denmark, Fysikvej, 2800 Kgs., Lyngby, Denmark.ORCID https://orcid.org/0000-0003-1588-338X
Khadijeh KhaliliDepartment of Energy Conversion and Storage, Technical University of Denmark, Fysikvej, 2800 Kgs., Lyngby, Denmark.ORCID https://orcid.org/0000-0002-2166-0636
Anders S GertsenDepartment of Energy Conversion and Storage, Technical University of Denmark, Fysikvej, 2800 Kgs., Lyngby, Denmark.ORCID https://orcid.org/0000-0002-4712-0339
Asbjørn MoltkeDepartment of Energy Conversion and Storage, Technical University of Denmark, Fysikvej, 2800 Kgs., Lyngby, Denmark.ORCID https://orcid.org/0000-0001-6310-6812
Xiaoyi ZhangX-ray Science Division, Argonne National Laboratory, Lemont, Illinois 60439, USA.
Tetsuo KatayamaJapan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo, Hyogo, 679-5198, Japan, and RIKEN Spring-8 Center, 1-1-1 Kouto, Sayo, Hyogo, 679-5148, Japan.ORCID https://orcid.org/0000-0002-2681-8316
Juan Maria García LastraDepartment of Energy Conversion and Storage, Technical University of Denmark, Fysikvej, 2800 Kgs., Lyngby, Denmark.ORCID https://orcid.org/0000-0001-5311-3656
Martin Meedom NielsenDepartment of Physics, Technical University of Denmark, Fysikvej, 2800 Kgs., Lyngby, Denmark.ORCID https://orcid.org/0000-0002-8135-434X
Shin-Ichi AdachiInstitute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba, Ibaraki, 305-0801, Japan and Department of Materials Structure Science, School of High Energy Accelerator Science, The Graduate University for Advanced Studies, 1-1, Oho, Tsukuba, Ibaraki, 305-0801, Japan.
Kristoffer HaldrupDepartment of Physics, Technical University of Denmark, Fysikvej, 2800 Kgs., Lyngby, Denmark.ORCID https://orcid.org/0000-0002-0565-6397
Jens Wenzel AndreasenDepartment of Energy Conversion and Storage, Technical University of Denmark, Fysikvej, 2800 Kgs., Lyngby, Denmark.ORCID https://orcid.org/0000-0002-3145-0229
Argonne National Laboratory · US

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Ultrafast, light-induced dynamics in copper-zinc-tin-sulfide (CZTS) photovoltaic nanoparticles are investigated through a combination of optical and x-ray transient absorption spectroscopy. Laser-pump, x-ray-probe spectroscopy on a colloidal CZTS nanoparticle ink yields element-specificity, which reveals a rapid photo-induced shift of electron density away from Cu-sites, affecting the molecular orbital occupation and structure of CZTS. We observe the formation of a stable charge-separated and thermally excited structure, which persists for nanoseconds and involves an increased charge density at the Zn sites. Combined with density functional theory calculations, the results provide new insight into the structural and electronic dynamics of CZTS absorbers for solar cells.

Identifiers

PMID33869663
PMCPMC8032451
OpenAlexW3148475424

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.