ArticleInorganic chemistry2021
Bioinspired Nucleophilic Attack on a Tungsten-Bound Acetylene: Formation of Cationic Carbyne and Alkenyl Complexes.
Article in Inorganic chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Proton-Coupled OAT Triggers C2H2 Activation in a Bioinspired Molybdenum Complex.Journal of the American Chemical Society · 2026Article
- Understanding the Carbyne Formation from CJournal of the American Chemical Society · 2024Article
- Vinyl-pyrazole as a biomimetic acetaldehyde surrogate.Chemical communications (Cambridge, England) · 2024Article
- Nucleophiles Target the Tungsten Center Over Acetylene in Biomimetic Models.Inorganic chemistry · 2024Article
- The Effect of Selenium-Based Ligands on Tungsten Acetylene Complexes.Inorganic chemistry · 2024Article
- Dioxygen Activation by a Bioinspired Tungsten(IV) Complex.Inorganic chemistry · 2023Article
- Inspired by Nature-Functional Analogues of Molybdenum and Tungsten-Dependent Oxidoreductases.Molecules (Basel, Switzerland) · 2022Review
- Synthesis and structure of two isomers of a molybdenum(II) 2-butyne complex stabilized by bioinspired S,N-bidentate ligands.Acta crystallographica. Section C, Structural chemistry · 2022Article
- The Effect of Pyridine-2-thiolate Ligands on the Reactivity of Tungsten Complexes toward Oxidation and Acetylene Insertion.Organometallics · 2021Article
- Synthesis and Reactivity of a Bioinspired Molybdenum(IV) Acetylene Complex.Organometallics · 2021Article
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Inspired by the proposed inner-sphere mechanism of the tungstoenzyme acetylene hydratase, we have designed tungsten acetylene complexes and investigated their reactivity. Here, we report the first intermolecular nucleophilic attack on a tungsten-bound acetylene (C
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