ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
Bis(pertrifluoromethylcatecholato)silane: Extreme Lewis Acidity Broadens the Catalytic Portfolio of Silicon.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed, 66 citations in OpenAlex.
- A Substrate-Dependent Redox Catalysis of Tellurenyl Species Involving Oxidation States +I, +II, and +IV.Inorganic chemistry · 2026Article
- Lewis superacids for catalytic reductions of stronger element-oxygen double bonds with hydrosilanes.Inorganic chemistry frontiers · 2026Article
- Alkoxyhydrosilane-facilitated cross-etherification reaction of secondary benzyl alcohol with aliphatic alcohol: synthesis of unsymmetrical dialkyl ethers.RSC advances · 2024Article
- Reversible C-H bond silylation with a neutral silicon Lewis acid.Chemical science · 2023Article
- Binding, Sensing, And Transporting Anions with Pnictogen Bonds: The Case of Organoantimony Lewis Acids.Journal of the American Chemical Society · 2023Review
- Silicon Catalyzed C-O Bond Ring Closing Metathesis of Polyethers.Angewandte Chemie (International ed. in English) · 2022Article
- Dihydrogen Activation with a Neutral, Intermolecular Silicon(IV)-Amine Frustrated Lewis Pair.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Hydrogen Bonding Networks Enable Brønsted Acid-Catalyzed Carbonyl-Olefin Metathesis.Angewandte Chemie (International ed. in English) · 2022Article
- What Distinguishes the Strength and the Effect of a Lewis Acid: Analysis of the Gutmann-Beckett Method.Angewandte Chemie (International ed. in English) · 2022Article
- Bis(perfluoropinacolato)silane: A Neutral Silane Lewis Superacid Activates Si-F Bonds.Angewandte Chemie (International ed. in English) · 2021Article
- Bis(pertrifluoromethylcatecholato)silane: Extreme Lewis Acidity Broadens the Catalytic Portfolio of Silicon.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
Given its earth abundance, silicon is ideal for constructing Lewis acids of use in catalysis or materials science. Neutral silanes were limited to moderate Lewis acidity, until halogenated catecholato ligands provoked a significant boost. However, catalytic applications of bis(perhalocatecholato)silanes were suffering from very poor solubility and unknown deactivation pathways. In this work, the novel per(trifluoromethyl)catechol, H
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Registered trials
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