ArticleAngewandte Chemie (International ed. in English)2021
Persistent peri-Heptacene: Synthesis and In Situ Characterization.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- High-Spin Porphyrin Polyradicals.ACS omega · 2026Article
- Highly Ordered Single DomainThe journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- A stable open-shell peri-hexacene with remarkable diradical character.Nature communications · 2025Article
- Leap from Diradicals to Tetraradicals by Topological Control of π-Conjugation.The Journal of organic chemistry · 2024Article
- Pathway to Polyradicals: A Planar and Fully π-Conjugated Organic Tetraradical(oid).The journal of physical chemistry letters · 2024Article
- Article
- Synthesis of π-Extended Thiele's and Chichibabin's Hydrocarbons and Effect of the π-Congestion on Conformations and Electronic States.Journal of the American Chemical Society · 2022Article
- Cove-Edged Hexa-peri-hexabenzo-bis-peri-octacene: Molecular Conformations and Amplified Spontaneous Emission.Angewandte Chemie (International ed. in English) · 2022Article
- NBN-Doped Bis-Tetracene and Peri-Tetracene: Synthesis and Characterization.Angewandte Chemie (International ed. in English) · 2021Article
- Persistent peri-Heptacene: Synthesis and In Situ Characterization.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
n-peri-Acenes (n-PAs) have gained interest as model systems of zigzag-edged graphene nanoribbons for potential applications in nanoelectronics and spintronics. However, the synthesis of n-PAs larger than peri-tetracene remains challenging because of their intrinsic open-shell character and high reactivity. Presented here is the synthesis of a hitherto unknown n-PA, that is, peri-heptacene (7-PA), in which the reactive zigzag edges are kinetically protected with eight 4-tBu-C
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