Evidence map›Paper›PMID 33848040›Full record

ArticleAngewandte Chemie (International ed. in English)2021

The Origin of Catalytic Benzylic C-H Oxidation over a Redox-Active Metal-Organic Framework.

Louis Kimberley, Alena M Sheveleva, Jiangnan Li, Joseph H Carter, Xinchen Kang, Gemma L Smith, Xue Han, Sarah J Day, Chiu C Tang, Floriana Tuna and 3 more

Abstract read
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In one paragraph

Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Review
  3. Review
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Louis KimberleyDepartment of Chemistry, University of Manchester, Manchester, M13 9PL, UK.
Alena M ShevelevaDepartment of Chemistry, University of Manchester, Manchester, M13 9PL, UK.ORCID http://orcid.org/0000-0001-6190-5944
Jiangnan LiDepartment of Chemistry, University of Manchester, Manchester, M13 9PL, UK.
Joseph H CarterDepartment of Chemistry, University of Manchester, Manchester, M13 9PL, UK.
Xinchen KangDepartment of Chemistry, University of Manchester, Manchester, M13 9PL, UK.
Gemma L SmithDepartment of Chemistry, University of Manchester, Manchester, M13 9PL, UK.
Xue HanDepartment of Chemistry, University of Manchester, Manchester, M13 9PL, UK.
Sarah J DayDiamond Light Source, Harwell Science Campus, Oxfordshire, OX11 0DE, UK.
Chiu C TangDiamond Light Source, Harwell Science Campus, Oxfordshire, OX11 0DE, UK.
Floriana TunaDepartment of Chemistry, University of Manchester, Manchester, M13 9PL, UK.
Eric J L McInnesDepartment of Chemistry, University of Manchester, Manchester, M13 9PL, UK.
Sihai YangDepartment of Chemistry, University of Manchester, Manchester, M13 9PL, UK.
Martin SchröderDepartment of Chemistry, University of Manchester, Manchester, M13 9PL, UK.ORCID http://orcid.org/0000-0001-6992-0700

Funding

Engineering and Physical Sciences Research Council EP/I011870H2020 European Research Council 742401
6 · The paper itself

Abstract

Selective oxidation of benzylic C-H compounds to ketones is important for the production of a wide range of fine chemicals, and is often achieved using toxic or precious metal catalysts. Herein, we report the efficient oxidation of benzylic C-H groups in a broad range of substrates under mild conditions over a robust metal-organic framework material, MFM-170, incorporating redox-active [Cu

Indexed as

benzylic oxidationcatalysiscopperelectron paramagnetic resonancemetal-organic framework

Identifiers

PMID33848040
PMCPMC8361671

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.