ArticleLangmuir : the ACS journal of surfaces and colloids2021
The Effect of Surface Entropy on the Heat of Non-Wetting Liquid Intrusion into Nanopores.
Article in Langmuir : the ACS journal of surfaces and colloids, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
7 citing papers in PubMed.
- Energetic and Structural Insights into Water Confined in Hydrophobic Nanopores.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026Article
- Crystallite Size Effects on the Heat of Water Intrusion/Extrusion into/from Metal-Organic Frameworks.The journal of physical chemistry letters · 2025Article
- Energetic Characteristics of Hydrophobic Porous Materials as Candidates for Manufacturing of Nanorockets.The journal of physical chemistry letters · 2024Article
- Surface Wetting Behaviors of Hydroxyl-Terminated Polybutadiene: Molecular Mechanism and Modulation.Polymers · 2024Article
- Partial Water Intrusion and Extrusion in Hydrophobic Nanopores for Thermomechanical Energy Dissipation.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Tuning Wetting-Dewetting Thermomechanical Energy for Hydrophobic Nanopores via Preferential Intrusion.The journal of physical chemistry letters · 2024Article
- Exploring the Heat of Water Intrusion into a Metal-Organic Framework by Experiment and Simulation.ACS applied materials & interfaces · 2024Article
Corrections and comments
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
On-demand access to renewable and environmentally friendly energy sources is critical to address current and future energy needs. To achieve this, the development of new mechanisms of efficient thermal energy storage (TES) is important to improve the overall energy storage capacity. Demonstrated here is the ideal concept that the thermal effect of developing a solid-liquid interface between a non-wetting liquid and hydrophobic nanoporous material can store heat to supplement current TES technologies. The fundamental macroscopic property of a liquid's surface entropy and its relationship to its solid surface are one of the keys to predict the magnitude of the thermal effect by the development of the liquid-solid interface in a nanoscale environment-driven through applied pressure. Demonstrated here is this correlation of these properties with the direct measurement of the thermal effect of non-wetting liquids intruding into hydrophobic nanoporous materials. It is shown that the model can resonably predict the heat of intrusion into rigid mesoporous silica and some microporous zeolite when the temperature dependence of the contact angle is applied. Conversely, intrusion into flexible microporous metal-organic frameworks requires further improvement. The reported results with further development have the potential to lead to the development of a new supplementary method and mechanim for TES.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.