Evidence map›Paper›PMID 33828616›Full record

ReviewBeilstein journal of organic chemistry2021

CF

Anthony J Fernandes, Armen Panossian, Bastien Michelet, Agnès Martin-Mingot, Frédéric R Leroux, Sébastien Thibaudeau

Abstract readReview
In one paragraph

Review in Beilstein journal of organic chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Review
  2. Article
  3. Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Anthony J FernandesUniversité de Strasbourg, Université de Haute-Alsace, CNRS, UMR 7042-LIMA, ECPM, 25 Rue Becquerel, 67087 Strasbourg, France.ORCID https://orcid.org/0000-0001-8372-7982
Armen PanossianUniversité de Strasbourg, Université de Haute-Alsace, CNRS, UMR 7042-LIMA, ECPM, 25 Rue Becquerel, 67087 Strasbourg, France.ORCID https://orcid.org/0000-0003-2317-1200
Bastien MicheletUniversité de Poitiers, CNRS, IC2MP, UMR 7285, Equipe "Synthèse Organique", 4 Rue Michel Brunet, 86073 Poitiers Cedex 9, France.
Agnès Martin-MingotUniversité de Poitiers, CNRS, IC2MP, UMR 7285, Equipe "Synthèse Organique", 4 Rue Michel Brunet, 86073 Poitiers Cedex 9, France.
Frédéric R LerouxUniversité de Strasbourg, Université de Haute-Alsace, CNRS, UMR 7042-LIMA, ECPM, 25 Rue Becquerel, 67087 Strasbourg, France.ORCID https://orcid.org/0000-0001-8900-5753
Sébastien ThibaudeauUniversité de Poitiers, CNRS, IC2MP, UMR 7285, Equipe "Synthèse Organique", 4 Rue Michel Brunet, 86073 Poitiers Cedex 9, France.ORCID https://orcid.org/0000-0002-6246-5829

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

"The extraordinary instability of such an "ion" accounts for many of the peculiarities of organic reactions" - Franck C. Whitmore (1932). This statement from Whitmore came in a period where carbocations began to be considered as intermediates in reactions. Ninety years later, pointing at the strong knowledge acquired from the contributions of famous organic chemists, carbocations are very well known reaction intermediates. Among them, destabilized carbocations - carbocations substituted with electron-withdrawing groups - are, however, still predestined to be transient species and sometimes considered as exotic ones. Among them, the CF

Indexed as

carbocationorganic synthesissuperelectrophiletrifluoromethyl

Identifiers

PMID33828616
PMCPMC7871035

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.