ArticleScience advances2021
Continuous color tuning of single-fluorophore emission via polymerization-mediated through-space charge transfer.
Article in Science advances, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Article
- Challenges and Opportunities in Machine Learning for Light-Emitting Polymers.Macromolecular rapid communications · 2026Review
- Heavy-atom functionalization promotes triplet-assisted charge-transfer exciton transport in organic cocrystals.Nature communications · 2026Article
- Polymerization-Inhibited Twisted Intramolecular Charge Transfer for Strong Molecular Aggregate Emission.ACS polymers Au · 2026Article
- Photoinduced charge-transfer dynamics in fluorescent electron donor-acceptor polymers.Chemical science · 2026Article
- Regioselective on-surface crystallization of one-dimensional organic barcode-like heterostructures of MOFs with fluorescent stripe patterns.Nature communications · 2025Article
- Excitation-Dependent Quadruple-Level Emission from an Isolated Molecule for Dynamic Information Encryption.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Self-Reporting Multiple Microscopic Stresses Through Tunable Microcapsule Arrays.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Designing High-Sensitivity Mechanochromic Luminescent Materials Through Friction-Induced Crystallization Strategy.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Photochemically and Thermally Programmed Optical Multi-States from a Single Diacetylene-Functionalized Cyanostilbene Luminogen.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Informatics colourizes polymers.Nature reviews. Chemistry · 2023Article
- Lanthanide Hexacyanidoruthenate Frameworks for Multicolor to White-Light Emission Realized by the Combination of d-d, d-f, and f-f Electronic Transitions.Inorganic chemistry · 2023Article
- Aggregation-Induced Emission Poly(meth)acrylates for PhotopatterningMacromolecules · 2022Article
- Supramolecular cuboctahedra with aggregation-induced emission enhancement and external binding ability.Chemical science · 2022Article
- Controlling Molecular Aggregation-Induced Emission by Controlled Polymerization.Molecules (Basel, Switzerland) · 2021Article
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Tuning emission color of molecular fluorophores is of fundamental interest as it directly reflects the manipulation of excited states at the quantum mechanical level. Despite recent progress in molecular design and engineering on single fluorophores, a systematic methodology to obtain multicolor emission in aggregated or solid states, which gives rise to practical implications, remains scarce. In this study, we present a general strategy to continuously tune the emission color of a single-fluorophore aggregate by polymerization-mediated through-space charge transfer (TSCT). Using a library of well-defined styrenic donor (D) polymers grown from an acceptor (A) fluorophore by controlled radical polymerization, we found that the solid-state emission color can be fine-tuned by varying three molecular parameters: (i) the monomer substituent, (ii) the end groups of the polymer, and (iii) the polymer chain length. Experimental and theoretical investigations reveal that the color tunability originates from the structurally dependent TSCT process that regulates charge transfer energy.
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