Evidence map›Paper›PMID 33825286›Full record

ReviewChemphyschem : a European journal of chemical physics and physical chemistry2021

Bridging the Gap: From Homogeneous to Heterogeneous Parahydrogen-induced Hyperpolarization and Beyond.

Eduard Y Chekmenev, Boyd M Goodson, Valerii I Bukhtiyarov, Igor V Koptyug

Open access · greenAbstract readReview
In one paragraph

Review in Chemphyschem : a European journal of chemical physics and physical chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
0.6field-weighted citation impact, top 39% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 5 citations in OpenAlex.

  1. Article
  2. Iron-CatalyzedJournal of the American Chemical Society · 2023
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 4 institutions in 2 countries.

Eduard Y ChekmenevDepartment of Chemistry, Integrative Biosciences (Ibio), Wayne State University Karmanos Cancer Institute (KCI), Detroit, MI 48202, USA.ORCID 0000-0002-8745-8801
Boyd M GoodsonSouthern Illinois University Department of Chemistry and Biochemistry Materials Technology Center, Carbondale, IL 62901, USA.
Valerii I BukhtiyarovBoreskov Institute of Catalysis, SB RAS, 5 Acad. Lavrentiev pr., Novosibirsk, 630090, Russia.
Igor V KoptyugInternational Tomography Center, SB RAS, 3A Institutskaya st., Novosibirsk, 630090, Russia.ORCID 0000-0003-3480-7649
Boreskov Institute of Catalysis · RUInternational Tomography Center · RURussian Academy of Sciences · RUSouthern Illinois University Carbondale · US

Funding

Molecular MRI of Brain Metabolism Enabled by Long-Lived Spin StatesR01EB029829 · NIBIB · NORTH CAROLINA STATE UNIVERSITY RALEIGH · PI THEIS, THOMAS · 2020 to 2020
$807k
Hyperpolarized Diethyl Ether for Sub-second Pulmonary MRIR21HL154032 · NHLBI · WAYNE STATE UNIVERSITY · PI CHEKMENEV, EDUARD · 2020 to 2021
$419k
Magnetic Resonance Spectroscopy and Molecular Imaging of Metabolic Pathways in CancerR21CA220137 · NCI · WAYNE STATE UNIVERSITY · PI CHEKMENEV, EDUARD · 2017 to 2019
$390k
DOD PRMRP W81XWH-15-1-0271DOD PRMRP W81XWH-15-1-0272DOD PRMRP W81XWH-20-1-0576DOD PRMRP W81XWH-20-1-0578NCI NIH HHS R21 CA220137NCI NIH HHS R21CA220137NHLBI NIH HHS R21 HL154032NIBIB NIH HHS 1R01EB029829NIBIB NIH HHS R01 EB029829NSF CHE-1904780NSF CHE-1905341RFBR 19-29-10003
6 · The paper itself

Abstract

Demonstration of parahydrogen-induced polarization effects in hydrogenations catalyzed by heterogeneous catalysts instead of metal complexes in a homogeneous solution has opened an entirely new dimension for parahydrogen-based research, demonstrating its applicability not only for the production of catalyst-free hyperpolarized liquids and gases and long-lived non-equilibrium spin states for potential biomedical applications, but also for addressing challenges of modern fundamental and industrial catalysis including advanced mechanistic studies of catalytic reactions and operando NMR and MRI of reactors. This essay summarizes the progress achieved in this field by highlighting the research contributed to it by our colleague and friend Kirill V. Kovtunov whose scientific career ended unexpectedly and tragically at the age of 37. His role in this research was certainly crucial, further enhanced by a vast network of his contacts and collaborations at the national and international level.

Indexed as

HydrogenMagnetic Resonance SpectroscopyReference StandardsHydrogenheterogeneous hydrogenationimmobilized metal complexesNMR signal enhancementparahydrogen-induced hyperpolarizationsupported metal catalysts

Identifiers

PMID33825286
PMCPMC8357055
OpenAlexW3139853929

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.