ArticleACS nano2021
Enhanced Organic Photocatalysis in Confined Flow through a Carbon Nitride Nanotube Membrane with Conversions in the Millisecond Regime.
Article in ACS nano, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Who cites it
8 citing papers in PubMed, 87 citations in OpenAlex.
- Advanced Multiscale Modeling for Revealing Anomalous Fluid Transport Induced by Confinement Interfacial Layer Reconstruction in Sub-10 nm Space.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Organic Synthesis Mediated by Carbon Nitride Photocatalysis and Photocharged Carbon Nitrides.Accounts of chemical research · 2026Article
- Amorphous/crystalline HTiNbONature communications · 2025Article
- Carbonaceous Material Modified MoOMolecules (Basel, Switzerland) · 2023Article
- Small-Scale Big Science: From Nano- to Atomically Dispersed Catalytic Materials.Small science · 2022Article
- Synthesis of Sulfonyl Chlorides from Aryldiazonium Salts Mediated by a Heterogeneous Potassium Poly(heptazine imide) Photocatalyst.ACS organic & inorganic Au · 2022Article
- Catalytic confinement effects in nanochannels: from biological synthesis to chemical engineering.Nanoscale advances · 2022Review
- Rational ion transport management mediated through membrane structures.Exploration (Beijing, China) · 2021Review
Corrections and comments
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Authors and funding
9 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Bioinspired nanoconfined catalysis has developed to become an important tool for improving the performance of a wide range of chemical reactions. However, photocatalysis in a nanoconfined environment remains largely unexplored. Here, we report the application of a free-standing and flow-through carbon nitride nanotube (CNN) membrane with pore diameters of 40 nm for confined photocatalytic reactions where reactants are in contact with the catalyst for <65 ms, as calculated from the flow. Due to the well-defined tubular structure of the membrane, we are able to assess quantitatively the photocatalytic performance in each of the parallelized single carbon nitride nanotubes, which act as spatially isolated nanoreactors. In oxidation of benzylamine, the confined reaction shows an improved performance when compared to the corresponding bulk reaction, reaching a turnover frequency of (9.63 ± 1.87) × 10
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.