ArticleACS sustainable chemistry & engineering2020
Fully Biobased Superpolymers of 2,5-Furandicarboxylic Acid with Different Functional Properties: From Rigid to Flexible, High Performant Packaging Materials.
Article in ACS sustainable chemistry & engineering, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 36 papers.
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The trial behind it
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Who cites it
36 citing papers in PubMed.
- Article
- Sustainable and High-Performance Food-Packaging Films from Poly(butylene 2,5-furanoate) and Poly(pentamethylene 2,5-furanoate) Blends.Polymers · 2026Article
- Biobased Random Copolymers From Furandicarboxylic Acid Isomers: Proof of Concept for an Integrated Biorefinery Approach Toward Outstanding Sustainable Food Packaging.Global challenges (Hoboken, NJ) · 2026Article
- Article
- Article
- The Evaluation of Eutectic Solvents as Catalysts for Mediating the Greener Synthesis of Poly(alkylene 2,5-furandicarboxylate)s.Molecules (Basel, Switzerland) · 2025Article
- Novel Superelastic Polyesters Based on 2,5-Furandicarboxylic Acid for Potential Use in Ophthalmic Surgery.Polymers · 2025Article
- Article
- Value-addition of carbohydrate-derived platform molecules using stoichiometric redox reagents.RSC advances · 2025Review
- Design and Characterization of Aromatic Copolyesters Containing Furan and Isophthalic Rings with Suitable Properties for Vascular Tissue Engineering.International journal of molecular sciences · 2025Article
- Article
- Electrospun Poly(butylene 2,5-furanoate) and Poly(pentamethylene 2,5-furanoate) Mats: Structure-Property Relationships and Thermo-Mechanical and Biological Characterization.Molecules (Basel, Switzerland) · 2025Article
- Melting Behavior of Compression Molded Poly(ester amide) from 2,5-Furandicarboxylic Acid.Polymers · 2024Article
- Fully Bio-Based Blends of Poly (Pentamethylene Furanoate) and Poly (Hexamethylene Furanoate) for Sustainable and Flexible Packaging.Polymers · 2024Article
- Study of the Crystal Structure and Hydrogen Bonding during Cold Crystallization of Poly(trimethylene 2,5-furandicarboxylate).Macromolecules · 2024Article
- Engineering an All-Biobased Solvent- and Styrene-Free Curable Resin.ACS polymers Au · 2023Article
- On the Selective Enzymatic Recycling of Poly(pentamethylene 2,5-furanoate)/Poly(lactic acid) Blends and Multiblock Copolymers.ACS sustainable chemistry & engineering · 2023Article
- Highly Flexible Poly(1,12-dodecylene 5,5'-isopropylidene-bis(ethyl 2-furoate)): A Promising Biobased Polyester Derived from a Renewable Cost-Effective Bisfuranic Precursor and a Long-Chain Aliphatic Spacer.Molecules (Basel, Switzerland) · 2023Article
- New Random Aromatic/Aliphatic Copolymers of 2,5-Furandicarboxylic and Camphoric Acids with Tunable Mechanical Properties and Exceptional Gas Barrier Capability for Sustainable Mono-Layered Food Packaging.Molecules (Basel, Switzerland) · 2023Article
- High Oxygen Barrier Polyester from 3,3'-Bifuran-5,5'-dicarboxylic Acid.ACS macro letters · 2023Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In the present paper, four fully biobased homopolyesters of 2,5-furandicarboxylic acid (2,5-FDCA) with a high molecular weight have been successfully synthesized by two-stage melt polycondensation, starting from the dimethyl ester of 2,5-FDCA and glycols of different lengths (the number of methylene groups ranged from 3 to 6). The synthesized polyesters have been first subjected to an accurate molecular characterization by NMR and gel-permeation chromatography. Afterward, the samples have been successfully processed into free-standing thin films (thickness comprised between 150 to 180 μm) by compression molding. Such films have been characterized from the structural (by wide-angle X-ray scattering and small-angle X-ray scattering), thermal (by differential scanning calorimetry and thermogravimetric analysis), mechanical (by tensile test), and gas barrier (by permeability measurements) point of view. The glycol subunit length was revealed to be the key parameter in determining the kind and fraction of ordered phases developed by the sample during compression molding and subsequent cooling. After storage at room temperature for one month, only the homopolymers containing the glycol subunit with an even number of -CH
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