ArticleNature chemistry2021
Polymerization of silanes through dehydrogenative Si-Si bond formation on metal surfaces.
Article in Nature chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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Who cites it
9 citing papers in PubMed.
- Conjugated Inorganic-Organic Hybrid Polymers with p-Block Elements.Angewandte Chemie (International ed. in English) · 2026Review
- Real-space investigations of on-surface intermolecular radical transfer reactions assisted by persistent radicals.Science advances · 2025Article
- Room-temperature selective cyclodehydrogenation on Au(111) via radical addition of open-shell resonance structures.Nature communications · 2024Article
- Universal inter-molecular radical transfer reactions on metal surfaces.Nature communications · 2024Article
- Applying a Deep-Learning-Based Keypoint Detection in Analyzing Surface Nanostructures.Molecules (Basel, Switzerland) · 2023Article
- On-surface synthesis of disilabenzene-bridged covalent organic frameworks.Nature chemistry · 2023Article
- Selective activation of four quasi-equivalent C-H bonds yields N-doped graphene nanoribbons with partial corannulene motifs.Nature communications · 2022Article
- On-Surface Synthesis of Unsaturated Hydrocarbon Chains through C-S Activation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Conformational evolution following the sequential molecular dehydrogenation of PMDI on a Cu(111) surface.Nanoscale advances · 2021Article
Corrections and comments
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Authors and funding
11 authors.
Funding
Abstract
Element-element double bonds of group 14 elements can be formed in solution, but generally only by applying harsh reductive conditions using sterically highly shielded tetryl halides as precursors. The two-dimensional confinement in surface-assisted polymerization represents a valuable alternative to access such reactive compounds, as it allows shielding of the labile entities without requiring bulky residues and catalytic activation of the reactive groups. Here, we demonstrate Si-Si bond formation in on-surface chemistry. Polymerization upon multiple Si-H bond dissociation and subsequent Si-Si bond formation was achieved on Au(111) and Cu(111) surfaces by using two different monomers, each containing two silicon functional groups (CH
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33782562What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.