ArticleNature chemistry2021
Immobilization of molecular catalysts on electrode surfaces using host-guest interactions.
Article in Nature chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
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Who cites it
22 citing papers in PubMed.
- Atomically precise catalysts design toward efficient waste plastic hydrogenolysis.Nature communications · 2026Review
- Electronic Coupling of Molecular Complexes to Au Electrodes Mediated via Host-Guest Interactions.Journal of the American Chemical Society · 2026Article
- Light-driven ammonia electrooxidation via carbon nitride-ruthenium molecular interfaces.Beilstein journal of nanotechnology · 2026Article
- Catalysts for Electrochemical Oxidation of Ammonia: A Comprehensive Review of Fundamentals and Optimization Strategies.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Template-stripped substrates with solvent-impermeable metal thin films.ACS nanoscience Au · 2025Article
- Electrocatalytic Ammonia Oxidation with Coordinatively Saturated Ruthenium Catalyst.Inorganic chemistry · 2025Article
- Electrocatalytic Oxidation of Ammonia by (Salen)ruthenium(III) Ammine Complexes: Direct Evidence for a Ruthenium(VI) Nitrido Active Intermediate.Journal of the American Chemical Society · 2025Article
- The Swiss Army Knife of Electrodes: Pillar[6]arene-Modified Electrodes for Molecular Electrocatalysis Over a Wide pH Range.Angewandte Chemie (International ed. in English) · 2025Article
- Host-guest-induced electronic state triggers two-electron oxygen reduction electrocatalysis.Nature communications · 2024Article
- C-H-activated CspNature communications · 2024Article
- Sustainable, low-cost, high-contrast electrochromic displays via host-guest interactions.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- A molecular view of single-atom catalysis toward carbon dioxide conversion.Chemical science · 2024Review
- Non-Covalent Interactions Mimic the Covalent: An Electrode-Orthogonal Self-Assembled Layer.Journal of the American Chemical Society · 2023Article
- Tuning Electrode Reactivity through Organometallic Complexes.ACS applied materials & interfaces · 2023Review
- Molecular Engineering of pH-Responsive Anchoring Systems onto Poly(ethylene glycol) Corona.Journal of the American Chemical Society · 2023Article
- Non-covalent ligand-oxide interaction promotes oxygen evolution.Nature communications · 2023Article
- Adaptive insertion of a hydrophobic anchor into a poly(ethylene glycol) host for programmable surface functionalization.Nature chemistry · 2023Article
- Heterogeneous Electrochemical Ammonia Oxidation with a Ru-bda Oligomer Anchored on Graphitic Electrodes via CH-π Interactions.ACS energy letters · 2023Article
- Hybrid Hydrogel Loaded with Chlorhexidine⊂β-CD-MSN Composites as Wound Dressing.International journal of nanomedicine · 2023Article
- A Covalent Organic Framework for Cooperative Water Oxidation.Journal of the American Chemical Society · 2022Article
Corrections and comments
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Anchoring molecular catalysts on electrode surfaces combines the high selectivity and activity of molecular systems with the practicality of heterogeneous systems. Molecular catalysts, however, are far less stable than traditional heterogeneous electrocatalysts, and therefore a method to easily replace anchored molecular catalysts that have degraded could make such electrosynthetic systems more attractive. Here we applied a non-covalent 'click' chemistry approach to reversibly bind molecular electrocatalysts to electrode surfaces through host-guest complexation with surface-anchored cyclodextrins. The host-guest interaction is remarkably strong and enables the flow of electrons between the electrode and the guest catalyst. Electrosynthesis in both organic and aqueous media was demonstrated on metal oxide electrodes, with stability on the order of hours. The catalytic surfaces can be recycled by controlled release of the guest from the host cavities and the readsorption of fresh guest.
Identifiers
33767362What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.