ArticleScience advances2021
Molecularly soldered covalent organic frameworks for ultrafast precision sieving.
Article in Science advances, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 33 papers.
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The trial behind it
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Who cites it
33 citing papers in PubMed, 345 citations in OpenAlex.
- Precise molecular sieving in polycrystalline covalent organic framework membranes.Science advances · 2026Article
- Heteroatom-Mediated Covalent Organic Framework Membranes With Nitrogen-Enriched Nanochannels for Efficient Desalination.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Scalable Art-Inspired Tessellated Covalent Organic Framework Membranes Enable Highly Selective Ion Separation.Angewandte Chemie (International ed. in English) · 2026Article
- Strain-Field-Induced Bandgap Opening in Bilayer Graphene.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Nanoarray-fortified ultra-durable nanofiber membrane via sequential crystallization.Nature communications · 2025Article
- Covalent/metal-organic framework membranes with tailored pore functionality for accurate ion separation.Chemical science · 2025Review
- Deep Eutectic Solvent-Mediated Engineering of Polyamide Membranes for High-Performance Loose Nanofiltration.Polymer science & technology (Washington, D.C.) · 2025Article
- Supramolecular nanocrystalline membranes with well-aligned subnanochannels for enhanced reverse osmosis desalination.Nature communications · 2025Article
- Creating free standing covalent organic framework membranes by nanocrystal suturing in sol gel solutions.Nature communications · 2025Article
- Interface-Confined Catalytic Synthesis of Anisotropic Covalent Organic Framework Nanofilm for Ultrafast Molecular Sieving.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- General synthesis of covalent organic frameworks under ambient condition within minutes via microplasma electrochemistry approach.Nature communications · 2025Article
- Turing covalent organic framework membranes via heterogeneous nucleation synthesis for organic solvent nanofiltration.Science advances · 2024Article
- Comediation of voltage gating and ion charge in MXene membrane for controllable and selective monovalent cation separation.Science advances · 2024Article
- Heterogeneous Covalent Organic Framework Membranes Mediated by Polycations for Efficient Ions Separation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Facet Engineering Boosts Interfacial Compatibility of Inorganic-Polymer Composites.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Optimizing selectivity via membrane molecular packing manipulation for simultaneous cation and anion screening.Science advances · 2024Article
- Enhancing ion selectivity by tuning solvation abilities of covalent-organic-framework membranes.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Covalent Organic Framework Membranes and Water Treatment.Journal of the American Chemical Society · 2024Review
- Enhancing the water permeability of composite NF membranes through the incorporation of organic ions in the aqueous phase.RSC advances · 2024Article
- Emerging environmentally friendly bio-based nanocomposites for the efficient removal of dyes and micropollutants from wastewater by adsorption: a comprehensive review.RSC advances · 2024Review
Corrections and comments
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Authors and funding
8 authors at 4 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The weak interlamellar interaction of covalent organic framework (COF) nanocrystals inhibit the construction of highly efficient ion/molecular sieving membranes owing to the inferior contaminant selectivity induced by defects in stacked COF membranes and stability issues. Here, a facile in situ molecularly soldered strategy was developed to fabricate defect-free ultrathin COF membranes with precise sieving abilities using the typical chemical environment for COF condensation polymerization and dopamine self-polymerization. The experimental data and density functional theory simulations proved that the reactive oxygen species generated during dopamine polymerization catalyze the nucleophilic reactions of the COF, thus facilitating the counter-diffusion growth of thin COF layers. Notably, dopamine can eliminate the defects in the stacked COF by soldering the COF crystals, fortifying the mechanical properties of the ultrathin COF membranes. The COF membranes exhibited ultrafast precision sieving for molecular separation and ion removal in both aqueous and organic solvents, which surpasses that of state-of-the-art membranes.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.