ArticleLangmuir : the ACS journal of surfaces and colloids2021
Electrogeneration of a Free-Standing Cytochrome c-Silica Matrix at a Soft Electrified Interface.
Article in Langmuir : the ACS journal of surfaces and colloids, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed, 13 citations in OpenAlex.
- Electroassisted Incorporation of Ferrocene Within Sol-Gel Silica Films to Enhance Electron Transfer-Part II: Boosting Protein Sensing with Polyelectrolyte-Modified Silica.Molecules (Basel, Switzerland) · 2025Article
- Electroassisted Incorporation of Ferrocene within Sol-Gel Silica Films to Enhance Electron Transfer.Molecules (Basel, Switzerland) · 2023Article
- Sensitive detection of noradrenaline in human whole blood based on Au nanoparticles embedded vertically-ordered silica nanochannels modified pre-activated glassy carbon electrodes.Frontiers in chemistry · 2023Article
- Electrodeless Synthesis of Low Dispersity Au Nanoparticles and Nanoclusters at an Immiscible Micro Water/Ionic Liquid Interface.Nanomaterials (Basel, Switzerland) · 2022Article
- Modulating the pro-apoptotic activity of cytochrome c at a biomimetic electrified interface.Science advances · 2021Article
- Vertically Ordered Mesoporous Silica-Nanochannel Film-Equipped Three-Dimensional Macroporous Graphene as Sensitive Electrochemiluminescence Platform.Frontiers in chemistry · 2021Article
Corrections and comments
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Authors and funding
5 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Interactions of a protein with a solid-liquid or a liquid-liquid interface may destabilize its conformation and hence result in a loss of biological activity. We propose here a method for the immobilization of proteins at an electrified liquid-liquid interface. Cytochrome c (Cyt c) is encapsulated in a silica matrix through an electrochemical process at an electrified liquid-liquid interface. Silica condensation is triggered by the interfacial transfer of cationic surfactant, cetyltrimethylammonium, at the lower end of the interfacial potential window. Cyt c is then adsorbed on the previously electrodeposited silica layer, when the interfacial potential, Δ
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