ArticleChemphyschem : a European journal of chemical physics and physical chemistry2021
Multidimensional Lewis Acidity: A Consistent Data Set of Chloride, Hydride, Methide, Water and Ammonia Affinities for 183 p-Block Element Lewis Acids.
Article in Chemphyschem : a European journal of chemical physics and physical chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed, 78 citations in OpenAlex.
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- Lewis-Acidic Properties and Catalytic Behavior of Hydroboration- and Diolysis-Derived NHC-Stabilized Borenium Cations.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Lewis acidity of a high-valent copper(iii) acetylacetonate.RSC advances · 2026Article
- Cis-Trans Isomerism and Hydride Thermodynamics Govern H2 Activation and Hydrogenation Activity in Indium(III) Pincer Complexes.Inorganic chemistry · 2026Article
- Origin of theJournal of the American Chemical Society · 2026Article
- Lewis superacids for catalytic reductions of stronger element-oxygen double bonds with hydrosilanes.Inorganic chemistry frontiers · 2026Article
- Dual Lewis Acid-Base Molecular Cages Facilitate Cooperative NChemphyschem : a European journal of chemical physics and physical chemistry · 2025Article
- Intermolecular SpAngewandte Chemie (International ed. in English) · 2025Article
- Lewis Acidity of the SbClAngewandte Chemie (International ed. in English) · 2025Article
- Hexaphenyl-1,2-Diphosphonium Dication [PhJournal of the American Chemical Society · 2025Article
- Intramolecular donor-stabilized tetra-coordinated germanium(iv) di-cations and their Lewis acidic properties.Chemical science · 2023Article
- Acidity Quantification and Structure Analysis of Amide-AlClMolecules (Basel, Switzerland) · 2023Article
- Probing the Impact of Solvent on the Strength of Lewis Acids via Fluorescent Lewis Adducts.Precision chemistry · 2023Article
- An easy-to-perform evaluation of steric properties of Lewis acids.Chemical science · 2023Article
- Computed ammonia affinity for evaluating Lewis acidity of organoboronates and organoboronamides.RSC advances · 2023Article
- Geometrically Constrained Cationic Low-Coordinate Tetrylenes: Highly Lewis Acidic σ-Donor Ligands in Catalytic Systems.Angewandte Chemie (International ed. in English) · 2022Article
- What Distinguishes the Strength and the Effect of a Lewis Acid: Analysis of the Gutmann-Beckett Method.Angewandte Chemie (International ed. in English) · 2022Article
- Probing the Boundaries between Lewis-Basic and Redox Behavior of a Parent Borylene.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
The computed fluoride ion affinity (FIA) is a widely applied descriptor to gauge Lewis acidity. Like every other single-parameter Lewis acidity scale, the FIA metric suffers from the one-dimensionality, that prohibits addressing Lewis acidity by the multidimensionality it inherently requires (i. e., reference Lewis base dependency). However, a systematic screening of computed affinities other than the FIA is much less developed. Herein, we extended our CCSD(T)/CBS benchmark of different density functionals and the DLPNO-CCSD(T) method for chloride (CIA), methide (MIA), hydride (HIA), water (WA), and ammonia (AA) affinities. The best performing methods are subsequently applied to yield nearly 800 affinities for 183 p-block element compounds of group 13-16 with an estimated accuracy of <10 kJ mol
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.