ArticleLangmuir : the ACS journal of surfaces and colloids2021
Wetting of Two-Component Drops: Marangoni Contraction Versus Autophobing.
Article in Langmuir : the ACS journal of surfaces and colloids, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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Who cites it
5 citing papers in PubMed.
- Polarity-Induced Reactive Wetting: Spreading and Retracting Sessile Water Drops.Langmuir : the ACS journal of surfaces and colloids · 2024Article
- Liquid-Liquid Phase Separation Induced by Vapor Transfer in Evaporative Binary Sessile Droplets.Langmuir : the ACS journal of surfaces and colloids · 2023Article
- Droplet duos on water display pairing, autonomous motion, and periodic eruption.Scientific reports · 2023Article
- How liquid-liquid phase separation induces active spreading.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Marangoni spreading and contracting three-component droplets on completely wetting surfaces.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The wetting properties of multicomponent liquids are crucial to numerous industrial applications. The mechanisms that determine the contact angles for such liquids remain poorly understood, with many intricacies arising due to complex physical phenomena, for example, due to the presence of surfactants. Here, we consider two-component drops that consist of mixtures of vicinal alkanediols and water. These diols behave surfactant-like in water. However, the contact angles of such mixtures on solid substrates are surprisingly large. We experimentally reveal that the contact angle is determined by two separate mechanisms of completely different nature, namely, Marangoni contraction (hydrodynamic) and autophobing (molecular). The competition between these effects can even inhibit Marangoni contraction, highlighting the importance of molecular structures in physico-chemical hydrodynamics.
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Registered trials
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