ArticleNature communications2021
Predicting wavelength-dependent photochemical reactivity and selectivity.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
18 citing papers in PubMed.
- Comparison Between Ultrasonic and Thermal Exfoliation for Molybdenum Disulfide Nanoparticles-A Multifunctional Study.Nanomaterials (Basel, Switzerland) · 2026Article
- Electron transfer from singlet fission dimers: possibilities and limitations.Chemical science · 2026Article
- Photoinduced Ring-Opening Polymerization of N-Carboxyanhydrides for the Preparation of Cross-Linked Polypeptide Gels.Angewandte Chemie (International ed. in English) · 2026Article
- Precision Photochemistry: Every Photon Counts.Angewandte Chemie (International ed. in English) · 2025Article
- Research and Developments of Heterogeneous Catalytic Technologies.Molecules (Basel, Switzerland) · 2025Review
- Sensitivity of mass-independent Sn isotope fractionation to UV radiation and magnetic fields.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- RAFT with Light: A User Guide to Using Thiocarbonylthio Compounds in Photopolymerizations.ACS polymers Au · 2025Article
- 1,2-Acyl transposition through photochemical skeletal rearrangement of 2,3-dihydrobenzofurans.Science (New York, N.Y.) · 2025Article
- Diverse reactivity of maleimides in polymer science and beyond.Polymer international · 2025Article
- Passive physical barrier modulates UVB-induced METosis-related MPO expression and activity, 25-hydroxyvitamin D3-1alpha-hydroxylase, and the shift of tissue-resident macrophages toward M1-associated iNOS.Frontiers in immunology · 2025Article
- Review
- Photochemical Action Plots Map Orthogonal Reactivity in Photochemical Release Systems.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Mechanistic Investigation, Wavelength-Dependent Reactivity, and Expanded Reactivity ofJournal of the American Chemical Society · 2024Article
- On photokinetics under polychromatic light.Frontiers in chemistry · 2024Article
- A practical perspective for chromatic orthogonality for implementing in photolithography.Scientific reports · 2023Article
- Sensitizer-controlled photochemical reactivityChemical science · 2022Article
- DNA Walkers for Biosensing Development.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Review
- Innovative Application of Three-Dimensional-Printed Breast Model-Aided Reduction Mammaplasty.Frontiers in surgery · 2022Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Predicting the conversion and selectivity of a photochemical experiment is a conceptually different challenge compared to thermally induced reactivity. Photochemical transformations do not currently have the same level of generalized analytical treatment due to the nature of light interaction with a photoreactive substrate. Herein, we bridge this critical gap by introducing a framework for the quantitative prediction of the time-dependent progress of photoreactions via common LEDs. A wavelength and concentration dependent reaction quantum yield map of a model photoligation, i.e., the reaction of thioether o-methylbenzaldehydes via o-quinodimethanes with N-ethylmaleimide, is initially determined with a tunable laser system. Combined with experimental parameters, the data are employed to predict LED-light induced conversion through a wavelength-resolved numerical simulation. The model is validated with experiments at varied wavelengths. Importantly, a second algorithm allows the assessment of competing photoreactions and enables the facile design of λ-orthogonal ligation systems based on substituted o-methylbenzaldehydes.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.