Evidence map›Paper›PMID 33719455›Full record

ArticleThe journal of physical chemistry letters2021

Investigation of Intramolecular Through-Space Charge-Transfer States in Donor-Acceptor Charge-Transfer Systems.

Shiv Kumar, Larissa Gomes Franca, Kleitos Stavrou, Ettore Crovini, David B Cordes, Alexandra M Z Slawin, Andrew P Monkman, Eli Zysman-Colman

Abstract read
In one paragraph

Article in The journal of physical chemistry letters, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.

0numbers the graph read from it
0cells of the map it votes in
15citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

15 citing papers in PubMed.

  1. Article
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  4. Article
  5. Article
  6. Review
  7. Review
  8. A Modular Approach to Tuning EmissiveThe journal of physical chemistry. B · 2024
    Article
  9. Sterically TunedACS applied materials & interfaces · 2024
    Article
  10. Article
  11. Article
  12. Article
  13. Article
  14. Acceptor-Donor-AcceptorResearch (Washington, D.C.) · 2022
    Article
  15. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Shiv KumarOrganic Semiconductor Centre, EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, Fife, U.K. KY16 9ST.
Larissa Gomes FrancaDepartment of Physics, Durham University, Durham, U.K. DH1 3LE.
Kleitos StavrouDepartment of Physics, Durham University, Durham, U.K. DH1 3LE.ORCID http://orcid.org/0000-0001-5868-3324
Ettore CroviniOrganic Semiconductor Centre, EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, Fife, U.K. KY16 9ST.
David B CordesOrganic Semiconductor Centre, EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, Fife, U.K. KY16 9ST.ORCID http://orcid.org/0000-0002-5366-9168
Alexandra M Z SlawinOrganic Semiconductor Centre, EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, Fife, U.K. KY16 9ST.
Andrew P MonkmanDepartment of Physics, Durham University, Durham, U.K. DH1 3LE.ORCID http://orcid.org/0000-0002-0784-8640
Eli Zysman-ColmanOrganic Semiconductor Centre, EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, Fife, U.K. KY16 9ST.ORCID http://orcid.org/0000-0001-7183-6022

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Commonly, thermally activated delayed fluorescence (TADF) emitters present a twisted donor-acceptor structure. Here, electronic communication is mediated through-bond via π-conjugation between donor and acceptor groups. A second class of TADF emitters are those where electronic communication between donor and acceptor moieties is mediated through-space. In these through-space charge-transfer (TSCT) architectures, the donor and acceptor groups are disposed in a pseudocofacial orientation and linked via a bridging group that is typically an arene (or heteroarene). In most of these systems, there is no direct evidence that the TSCT is the dominant contributor to the communication between the donor and acceptor. Herein we investigate the interplay between through-bond localized excited (LE) and charge-transfer (CT) states and the TSCT in a rationally designed emitter,

Identifiers

PMID33719455
PMCPMC8041366

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.