ReviewAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2021
Reversible Deactivation Radical Polymerization: From Polymer Network Synthesis to 3D Printing.
Review in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
23 citing papers in PubMed.
- Ultrafast and high-precision 3D printingChemical science · 2026Article
- Controlled polymerization of methyl acrylate in the presence of copper MOF (BasoliteScientific reports · 2026Article
- Organocatalytic atom transfer radical polymerization with light and pH dual-gated regulation.Nature communications · 2026Article
- Photo-excited extracellular electron transfer of electroactive microorganism triggers RAFT polymerization.Nature communications · 2025Article
- Recyclable RAFT-3D printing.Chemical science · 2025Article
- Molecular Weight Control in Frontal Ring-Opening Metathesis Polymerization.Angewandte Chemie (International ed. in English) · 2025Article
- Highly Entangled Hydrogels by Photoiniferter-Mediated Polymerization.Angewandte Chemie (International ed. in English) · 2025Article
- Exploring the potential of polymers: advancements in oral nanocarrier technology.Beilstein journal of nanotechnology · 2025Review
- Three-Dimensional Printing of Hydrogel Blend Tissue Engineering Scaffolds with In Situ Delivery of Anticancer Drug for Treating Melanoma Resection-Induced Tissue Defects.Journal of functional biomaterials · 2024Article
- Programming Mechanical Properties through Encoded Network Topologies.Journal of polymer science (2020) · 2024Article
- Polymeric Nanoparticles for Drug Delivery.Chemical reviews · 2024Review
- Fluorescence-readout as a powerful macromolecular characterisation tool.Chemical science · 2023Review
- Red-light-mediated Barton decarboxylation reaction and one-pot wavelength-selective transformations.Chemical science · 2023Article
- Nanotoxicity of multifunctional stoichiometric cobalt oxide nanoparticles (SCoONPs) with repercussions toward apoptosis, necrosis, and cancer necrosis factor (TNF-α) at nano-biointerfaces.Toxicology research · 2023Review
- Multi-Stimuli Responsive Sequence Defined Multi-Arm Star Diblock Copolymers for Controlled Drug Release.JACS Au · 2023Article
- Gelation in Photoinduced ATRP with Tuned Dispersity of the Primary Chains.Macromolecules · 2023Article
- Novel Formulations Containing Fluorescent Sensors to Improve the Resolution of 3D Prints.International journal of molecular sciences · 2022Article
- Rational Design of Photocatalysts for Controlled Polymerization: Effect of Structures on Photocatalytic Activities.Chemical reviews · 2022Review
- Hydrogel Polyester Scaffolds via Direct-Ink-Writing of Ad Hoc Designed Photocurable Macromonomer.Polymers · 2022Article
- Controllable synthesis and structural design of novel all-organic polymers toward high energy storage dielectrics.Frontiers in chemistry · 2022Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
3D printing has changed the fabrication of advanced materials as it can provide customized and on-demand 3D networks. However, 3D printing of polymer materials with the capacity to be transformed after printing remains a great challenge for engineers, material, and polymer scientists. Radical polymerization has been conventionally used in photopolymerization-based 3D printing, as in the broader context of crosslinked polymer networks. Although this reaction pathway has shown great promise, it offers limited control over chain growth, chain architecture, and thus the final properties of the polymer networks. More fundamentally, radical polymerization produces dead polymer chains incapable of postpolymerization transformations. Alternatively, the application of reversible deactivation radical polymerization (RDRP) to polymer networks allows the tuning of network homogeneity and more importantly, enables the production of advanced materials containing dormant reactivatable species that can be used for subsequent processes in a postsynthetic stage. Consequently, the opportunities that (photoactivated) RDRP-based networks offer have been leveraged through the novel concepts of structurally tailored and engineered macromolecular gels, living additive manufacturing and photoexpandable/transformable-polymer networks. Herein, the advantages of RDRP-based networks over irreversibly formed conventional networks are discussed.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.