ReviewSmall (Weinheim an der Bergstrasse, Germany)2021
Operando Surface Spectroscopy and Microscopy during Catalytic Reactions: From Clusters via Nanoparticles to Meso-Scale Aggregates.
Review in Small (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
28 citing papers in PubMed, 82 citations in OpenAlex.
- Predicting Catalyst Performance From Pt/CeOAngewandte Chemie (International ed. in English) · 2026Article
- Succinate-assisted synthesis of ZnO-CuO heterostructure electrocatalysts for tunable hydrogen evolution reaction.RSC advances · 2026Article
- Unexpected Reactivity of Zirconium Carbide on Nickel/Yttria-Stabilized Zirconia Boosts COChemistry of materials : a publication of the American Chemical Society · 2026Article
- Recent Advances and Perspectives of Metal Clusters for Electrochemical Nitrogen Reduction.ChemPlusChem · 2026Review
- Electrochemical imaging of thermochemical catalysis.Nature catalysis · 2026Article
- Synergy of Oxygen and Water in Ceria-Catalyzed Direct Conversion of Methane to Methanol under Continuous Flow.ACS catalysis · 2025Article
- Femtosecond Laser Generation of LaCoOACS applied nano materials · 2025Article
- Influence of MXene and TiOACS catalysis · 2025Article
- From design to efficiency: cobalt-based MOFs for efficient and stable electrocatalysis in hydrogen and oxygen evolution reactions.RSC advances · 2025Article
- Modeling Heterogeneous Catalysis Using Quantum Computers: An Academic and Industry Perspective.Journal of chemical information and modeling · 2025Review
- Comprehensive Understanding of Elemental Doping and Substitution of Ni-Rich Cathode Materials for Lithium-Ion Batteries via In Situ Operando Analyses.Small science · 2024Article
- Defect-Rich CuZn Nanoparticles for Model Catalysis Produced by Femtosecond Laser Ablation.ACS applied materials & interfaces · 2024Article
- A feasible interlayer strategy for simultaneous light and heat management in photothermal catalysis.iScience · 2024Article
- Highly Stable Self-Cleaning Paints Based on Waste-Valorized PNC-Doped TiOACS catalysis · 2024Article
- Understanding the Dynamic Aggregation in Single-Atom Catalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Review
- Mesoporous Ag@WOScientific reports · 2024Article
- Microalgae-derived CoRSC advances · 2024Article
- Article
- Partial Oxidation of Bio-methane over Nickel Supported on MgO-ZrOTopics in catalysis · 2023Article
- Kinetic and Computational Studies of CO Oxidation and PROX on Cu/CeOTopics in catalysis · 2023Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
1 author at 1 institution in 1 country.
Funding
Abstract
Operando characterization of working catalysts, requiring per definitionem the simultaneous measurement of catalytic performance, is crucial to identify the relevant catalyst structure, composition and adsorbed species. Frequently applied operando techniques are discussed, including X-ray absorption spectroscopy, near ambient pressure X-ray photoelectron spectroscopy and infrared spectroscopy. In contrast to these area-averaging spectroscopies, operando surface microscopy by photoemission electron microscopy delivers spatially-resolved data, directly visualizing catalyst heterogeneity. For thorough interpretation, the experimental results should be complemented by density functional theory. The operando approach enables to identify changes of cluster/nanoparticle structure and composition during ongoing catalytic reactions and reveal how molecules interact with surfaces and interfaces. The case studies cover the length-scales from clusters via nanoparticles to meso-scale aggregates, and demonstrate the benefits of specific operando methods. Restructuring, ligand/atom mobility, and surface composition alterations during the reaction may have pronounced effects on activity and selectivity. The nanoscale metal/oxide interface steers catalytic performance via a long ranging effect. Combining operando spectroscopy with switching gas feeds or concentration-modulation provides further mechanistic insights. The obtained fundamental understanding is a prerequisite for improving catalytic performance and for rational design.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.