ArticlePolymers2021
Mechanism Identification and Kinetics Analysis of Thermal Degradation for Carbon Fiber/Epoxy Resin.
Article in Polymers, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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13 citing papers in PubMed, 58 citations in OpenAlex.
- The Effect of Silicone Modification on the Thermo-Oxidative Degradation and Mechanical Property Retention of CFRP Laminates.Polymers · 2026Article
- Epoxy Blends Containing Melamine Phosphate-Based Flame Retardants: Thermal and Flammability Performance.Materials (Basel, Switzerland) · 2026Article
- Pyrolysis Kinetics and Thermodynamics of Ambient-Pressure-Dried Silica Aerogels Modified with Tri-, Di- and Mono-Methylsilyl Groups.Gels (Basel, Switzerland) · 2026Article
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- Potential Application of Epoxy Powder Coating Waste in Concrete: Strength Properties and Durability of Concrete.Materials (Basel, Switzerland) · 2026Article
- Preparation and Properties of Magnetically Responsive Graphene/Boron Nitride/Iron Oxide Filler Composite Epoxy Resin Materials.Nanomaterials (Basel, Switzerland) · 2025Article
- Effects of the Backbone's Structures on the Curing Behaviors and Properties of Phthalonitrile Containing Benzoxazine Rings.Molecules (Basel, Switzerland) · 2024Article
- Molecular dynamics study on the influence of thermal aging on the mechanical properties of epoxy resins for high voltage bushing.Journal of molecular modeling · 2024Article
- Article
- Pyrolysis Kinetics Analysis and Prediction for Carbon Fiber-Reinforced Epoxy Composites.Polymers · 2023Article
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- Improved Ablative Properties of Nanodiamond-Reinforced Carbon Fiber-Epoxy Matrix Composites.Polymers · 2021Article
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
For carbon fiber epoxy resin used in aerostructure, thermal degradation mechanism and kinetics play an important role in the evaluation of thermal response and combustion characteristics. However, the thermal decomposition process and mechanism are difficult to unify strictly due to the complexity of the components from different suppliers. In the present study, a product of carbon fiber epoxy resin made by AVIC (Aviation Industry Corporation of China) composite corporation is examined to identify its thermal degradation mechanism and pyrolysis products by measurements, including simultaneous thermal analysis, Fourier transform infrared spectroscopy and mass spectrometry, establish the kinetic model by Kissinger/Friedman/Ozawa/Coats-Redfern methods. The results show thermal degradation occurs in three steps under the inert atmosphere, but in four steps under air atmosphere, respectively. The first two steps in both environments are almost the same, including drying, carbon dioxide escape and decomposition of the epoxy resin. In the third step of inert atmosphere, phenol is formed, methane decreases, carbon monoxide basically disappears and carbon dioxide production increases. However, in air, thermal oxidation of the carbonaceous residues and intermolecular carbonization are observed. Furthermore, thermal degradation reaction mechanism submits to the F
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