ReviewMolecules (Basel, Switzerland)2021
Microwaves as "Co-Catalysts" or as Substitute for Catalysts in Organophosphorus Chemistry.
Review in Molecules (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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4 citing papers in PubMed.
- A Novel Method of Coupling In Situ Time-Resolved FTIR and Microwave Irradiation: Application to the Monitoring of Quinoxaline Derivatives Synthesis.Molecules (Basel, Switzerland) · 2025Article
- Recent advances in the electrochemical synthesis of organophosphorus compounds.Beilstein journal of organic chemistry · 2025Review
- Deamination of 1-Aminoalkylphosphonic Acids: Reaction Intermediates and Selectivity.Molecules (Basel, Switzerland) · 2022Article
- Green and Effective Preparation of α-Hydroxyphosphonates by Ecocatalysis.Molecules (Basel, Switzerland) · 2022Article
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Abstract
The purpose of this review is to summarize the importance of microwave (MW) irradiation as a kind of catalyst in organophosphorus chemistry. Slow or reluctant reactions, such as the Diels-Alder cycloaddition or an inverse-Wittig type reaction, may be performed efficiently under MW irradiation. The direct esterification of phosphinic and phosphonic acids, which is practically impossible on conventional heating, may be realized under MW conditions. Ionic liquid additives may promote further esterifications. The opposite reaction, the hydrolysis of P-esters, has also relevance among the MW-assisted transformations. A typical case is when the catalysts are substituted by MWs, which is exemplified by the reduction of phosphine oxides, and by the Kabachnik-Fields condensation affording α-aminophosphonic derivatives. Finally, the Hirao P-C coupling reaction may serve as an example, when the catalyst may be simplified under MW conditions. All of the examples discussed fulfill the expectations of green chemistry.
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