Evidence map›Paper›PMID 33667335›Full record

ArticleACS nano2021

Surface-Enhanced Raman Scattering and Surface-Enhanced Infrared Absorption by Plasmon Polaritons in Three-Dimensional Nanoparticle Supercrystals.

Niclas S Mueller, Emanuel Pfitzner, Yu Okamura, Georgy Gordeev, Patryk Kusch, Holger Lange, Joachim Heberle, Florian Schulz, Stephanie Reich

Abstract read
In one paragraph

Article in ACS nano, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.

0numbers the graph read from it
0cells of the map it votes in
25citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

25 citing papers in PubMed.

  1. Article
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  6. Resonant Enhancement of Photolysis through Plasmon-Vibrational Coupling.Journal of the American Chemical Society · 2026
    Article
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  17. Direct Bottom-UpChemical reviews · 2023
    Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Niclas S MuellerDepartment of Physics, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin, Germany.ORCID http://orcid.org/0000-0002-8688-1974
Emanuel PfitznerDepartment of Physics, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin, Germany.ORCID http://orcid.org/0000-0003-0028-3242
Yu OkamuraDepartment of Physics, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin, Germany.
Georgy GordeevDepartment of Physics, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin, Germany.ORCID http://orcid.org/0000-0002-3273-2105
Patryk KuschDepartment of Physics, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin, Germany.ORCID http://orcid.org/0000-0001-9180-786X
Holger LangeInstitute of Physical Chemistry, University of Hamburg, Grindelallee 117, 20146 Hamburg, Germany.ORCID http://orcid.org/0000-0002-4236-2806
Joachim HeberleDepartment of Physics, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin, Germany.ORCID http://orcid.org/0000-0001-6321-2615
Florian SchulzInstitute of Physical Chemistry, University of Hamburg, Grindelallee 117, 20146 Hamburg, Germany.ORCID http://orcid.org/0000-0003-4440-3680
Stephanie ReichDepartment of Physics, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin, Germany.ORCID http://orcid.org/0000-0002-2391-0256

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Surface-enhanced vibrational spectroscopy strongly increases the cross section of Raman scattering and infrared absorption, overcoming the limited sensitivity and resolution of these two powerful analytic tools. While surface-enhanced setups with maximum enhancement have been studied widely in recent years, substrates with reproducible, uniform enhancement have received less attention although they are required in many applications. Here, we show that plasmonic supercrystals are an excellent platform for enhanced spectroscopy because they possess a high density of hotspots in the electric field. We describe the near field inside the supercrystal within the framework of plasmon polaritons that form due to strong light-matter interaction. From the polariton resonances we predict resonances in the far-field enhancement for Raman scattering and infrared absorption. We verify our predictions by measuring the vibrations of polystyrene molecules embedded in supercrystals of gold nanoparticles. The intensity of surface-enhanced Raman scattering is uniform within 10% across the crystal with a peak integrated enhancement of up to 300 and a peak hotspot enhancement of 10

Indexed as

coupled oscillatorgold nanoparticlesplasmonicspolaritonsupercrystalssurface-enhanced infrared absorption spectroscopy (SEIRAS)surface-enhanced Raman scattering (SERS)

Identifiers

PMID33667335
PMCPMC7992191

What OpenQuestion holds

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LicenceCC BY-NC-ND
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.