ArticleScientific reports2021
Molecular fusion of surfactant and Lewis-acid properties for attacking dirt by catalytic bond cleavage.
Article in Scientific reports, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed, 8 citations in OpenAlex.
- A Versatile Route to Shape Polymer Nanoparticles by Deforming Nanoreactors Made from Magnetic Surfactants.Angewandte Chemie (International ed. in English) · 2025Article
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2 authors at 2 institutions in 1 country.
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Abstract
The capability of ordinary surfactants in solubilizing hydrophobic compounds can come to a limit, if the extension of a contaminant is too large. An attractive goal is the development of surfactants which can actively reduce the size of dirt. Because strong Lewis acids are known to catalyze both bond formation and cleavage, an integration into the surfactant's molecular framework is tempting. End-group functionalized hepta-dentate ligands, which coordinate to metal ions preventing deactivation by hydrolysis over a broad range of pH values while maintaining strong Lewis-acidity, are herein presented. After proof of amphiphilicity and surfactant characteristics, catalytic properties are investigated for different reactions including the cleavage of proteins. The compounds perform better than benchmark catalysts concerning the attack of unreactive amide bonds. A study with two Sc
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