Evidence map›Paper›PMID 33661562›Full record

ArticleAngewandte Chemie (International ed. in English)2021

Electrophotocatalytic C-H Heterofunctionalization of Arenes.

He Huang, Tristan H Lambert

Open access · greenAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.

0numbers the graph read from it
0cells of the map it votes in
22citing papers in PubMed
11.7field-weighted citation impact, top 1% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

22 citing papers in PubMed, 137 citations in OpenAlex.

  1. Review
  2. Review
  3. Review
  4. Article
  5. Article
  6. Article
  7. Direct C-H Hydroxylation ofJournal of the American Chemical Society · 2024
    Article
  8. Article
  9. Selective C(spNature communications · 2023
    Article
  10. Photoelectrochemical oxidative C(spNature communications · 2023
    Article
  11. Review
  12. Review
  13. Catalytic Synthesis of Cyclopropenium Cations with Rh-Carbynoids.Journal of the American Chemical Society · 2022
    Article
  14. Article
  15. Review
  16. A Perspective on Late-Stage Aromatic C-H Bond Functionalization.Journal of the American Chemical Society · 2022
    Article
  17. Review
  18. Review
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors at 1 institution in 1 country.

He HuangDepartment of Chemistry and Chemical Biology, Cornell University, 122 Baker Laboratory, Ithaca, NY, 14853, USA.
Tristan H LambertDepartment of Chemistry and Chemical Biology, Cornell University, 122 Baker Laboratory, Ithaca, NY, 14853, USA.ORCID 0000-0002-7720-3290
Cornell University · US

Funding

CATALYTIC PLATFORMS USING AROMATIC IONS AND OTHER CHARGED SPECIESR35GM127135 · NIGMS · CORNELL UNIVERSITY · PI Tristan H Lambert · 2018 to 2026
$4.4M
NIGMS NIH HHS R35 GM127135
6 · The paper itself

Abstract

The electrophotocatalytic heterofunctionalization of arenes is described. Using 2,3-dichloro-5,6-dicyanoquinone (DDQ) under a mild electrochemical potential with visible-light irradiation, arenes undergo oxidant-free hydroxylation, alkoxylation, and amination with high chemoselectivity. In addition to batch reactions, an electrophotocatalytic recirculating flow process is demonstrated, enabling the conversion of benzene to phenol on a gram scale.

Indexed as

BenzeneBenzoquinonesCatalysisElectrochemical TechniquesLightMolecular StructurePhenolsBenzeneBenzoquinonesdichlorodicyanobenzoquinonePhenolsalkoxylationaminationelectrophotocatalysishydroxylationphotochemistry

Identifiers

PMID33661562
PMCPMC8099024
OpenAlexW3134784652

What OpenQuestion holds

Textmetadata
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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.