ArticleThe journal of physical chemistry. B2021
Vibrationally Assisted Direct Intersystem Crossing between the Same Charge-Transfer States for Thermally Activated Delayed Fluorescence: Analysis by Marcus-Hush Theory Including Reorganization Energy.
Article in The journal of physical chemistry. B, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Solvent Polarity as a Diagnostic for Vibronic/Vibrational Coherences Distinction in an Efficient TADF-TTA Switchable Emitter.Small science · 2026Article
- Millisecond-Delayed Fluorescence in Heavy-Halogen-Substituted TADF Emitters for Air-Pressure Sensing.ACS applied materials & interfaces · 2026Article
- Temperature dependency of energy shift of excitonic states in a donor-acceptor type TADF molecule.Nature communications · 2025Article
- Dynamics of vibrationally coupled intersystem crossing in state-of-the-art organic optoelectronic materials.Communications chemistry · 2025Article
- Halogen Impact on the Supramolecular Organization of Chiral Phthalimide Emitters Displaying Room Temperature Phosphorescence.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- Shedding light on thermally-activated delayed fluorescence.Chemical science · 2024Review
- Application of the Heavy-Atom Effect for (Sub)microsecond Thermally Activated Delayed Fluorescence and an All-Organic Light-Emitting Device with Low-Efficiency Roll-off.ACS applied materials & interfaces · 2024Article
- Rational Design of Highly Efficient Orange-Red/Red Thermally Activated Delayed Fluorescence Emitters with Submicrosecond Emission Lifetimes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Carrier Transport in Colloidal Quantum Dot Intermediate Band Solar Cell Materials Using Network Science.International journal of molecular sciences · 2023Article
- Organic Disordered Semiconductors as Networks Embedded in Space and Energy.Nanomaterials (Basel, Switzerland) · 2022Article
- Anomalous (Exergonic) Behavior in the Transfer of Electrons between Donors and Acceptors: Mobility, Energy, Caloric Capacity, and Entropy.ACS omega · 2022Article
- Regiochemistry of Donor Dendrons Controls the Performance of Thermally Activated Delayed Fluorescence Dendrimer Emitters for High Efficiency Solution-Processed Organic Light-Emitting Diodes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Thermally activated delayed fluorescence (TADF) has recently become an extensively investigated phenomenon due to its high potential for application in organic optoelectronics. Currently, there is still lack of a model describing correctly basic photophysical parameters of organic TADF emitters. This article presents such a photophysical model describing the rates of intersystem crossing (ISC), reverse ISC (rISC), and radiative deactivation in various media and emphasizing key importance of molecular vibrations on the example of a popular TADF dye 9,10-dihydro-9,9-dimethyl-10-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-acridine (DMAC-TRZ). The presented experimental and theoretical investigations prove that ISC and rISC can occur efficiently between the singlet and triplet states of the same charge-transfer nature (
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Registered trials
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