ArticleOrganic letters2021
Decatungstate as Direct Hydrogen Atom Transfer Photocatalyst for SOMOphilic Alkynylation.
Article in Organic letters, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed.
- Interpreting terminal selectivity in undirected C(spChemical science · 2026Review
- Metal-free radical borylations: mechanisms, catalytic strategies, and synthetic applications.Chemical science · 2026Review
- Photochemical Synthesis of Ynones from Aryl Aldehydes and Sulfone-Based Alkynes.The Journal of organic chemistry · 2025Article
- Unified Hydrogen Atom Transfer Approach To Construct Vicinal Functionality.Organic letters · 2025Article
- L-Cysteine-Catalysed Hydration of Activated Alkynes.Angewandte Chemie (International ed. in English) · 2025Article
- Scalable deoxygenative alkynylation of alcohols via flow photochemistry.Communications chemistry · 2024Article
- α-Functionalisation of Cyclic Sulfides Enabled by Lithiation Trapping.Angewandte Chemie (International ed. in English) · 2024Article
- SOMOphilic alkyne vs radical-polar crossover approaches: The full story of the azido-alkynylation of alkenes.Beilstein journal of organic chemistry · 2024Article
- Development and application of decatungstate catalyzed C-HChemical science · 2023Review
- Azido-alkynylation of alkenes through radical-polar crossover.Chemical science · 2023Article
- Recent Advances in C-H Functionalisation through Indirect Hydrogen Atom Transfer.Molecules (Basel, Switzerland) · 2023Review
- Asymmetric imino-acylation of alkenes enabled by HAT-photo/nickel cocatalysis.Chemical science · 2023Article
- Ruthenium-Catalyzed C-C Coupling of Terminal Alkynes with Primary Alcohols or Aldehydes: α,β-Acetylenic Ketones (Ynones) via Oxidative Alkynylation.Angewandte Chemie (International ed. in English) · 2023Article
- Functionalisation of ethereal-based saturated heterocycles with concomitant aerobic C-H activation and C-C bond formation.Chemical science · 2022Article
- Photoinduced inverse Sonogashira coupling reaction.Chemical science · 2022Article
- Radical C(sp3)-H functionalization and cross-coupling reactions.Nature reviews. Chemistry · 2022Article
- Decatungstate-photocatalysed C(spChemical communications (Cambridge, England) · 2022Article
- Visible Light-Induced Transition Metal Catalysis.Chemical reviews · 2022Review
- Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C-H Bonds Elaboration.Chemical reviews · 2022Review
- SOMOphilic Alkynylation of Unreactive Alkenes Enabled by Iron-Catalyzed Hydrogen Atom Transfer.Molecules (Basel, Switzerland) · 2021Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A versatile approach for the alkynylation of a variety of aliphatic hydrogen donors, including alkanes, is reported. We used tetrabutylammonium decatungstate as photocatalyst to generate organoradicals from C-H/Si-H bonds via hydrogen atom transfer. The latter intermediates underwent SOMOphilic alkynylation by methanesulfonyl alkynes to afford internal alkynes upon loss of a sulfonyl radical. The effect of different radicofugal groups on the reaction outcome was evaluated and rationalized via a combined experimental and computational approach.
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