ArticleAngewandte Chemie (International ed. in English)2021
Massive Pressure Amplification by Stimulated Contraction of Mesoporous Frameworks*.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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Who cites it
7 citing papers in PubMed, 26 citations in OpenAlex.
- Negative gas adsorption transitions and pressure amplification phenomena in porous frameworks.Chemical Society reviews · 2025Review
- Nanoporous Frameworks with High Porosity and Unexpected Rigid Framework Topologies Based on Odd-Numbered Ring-Expanded Linkers.Small science · 2023Article
- On the role of history-dependent adsorbate distribution and metastable states in switchable mesoporous metal-organic frameworks.Nature communications · 2023Article
- Cooperative light-induced breathing of soft porous crystals via azobenzene buckling.Nature communications · 2022Article
- Integration of Fluorescent Functionality into Pressure-Amplifying Metal-Organic Frameworks.Chemistry of materials : a publication of the American Chemical Society · 2021Article
- Massive Pressure Amplification by Stimulated Contraction of Mesoporous Frameworks*.Angewandte Chemie (International ed. in English) · 2021Article
- Charting the Complete Thermodynamic Landscape of Gas Adsorption for a Responsive Metal-Organic Framework.Journal of the American Chemical Society · 2021Article
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 2 countries.
Funding
Abstract
Herein we demonstrate mesoporous frameworks interacting with carbon dioxide leading to stimulated structural contractions and massive out-of-equilibrium pressure amplification well beyond ambient pressure. Carbon dioxide, a non-toxic and non-flammable working medium, is promising for the development of pressure-amplifying frameworks for pneumatic technologies and safety systems. The strong interaction of the fluid with the framework even contracts DUT-46, a framework hitherto considered as non-flexible. Synchrotron-based in situ PXRD/adsorption experiments reveal the characteristic contraction pressure for DUT-49 pressure amplification in the range of 350-680 kPa. The stimulated framework contraction expels 1.1 to 2.4 mmol g
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.