ArticleAngewandte Chemie (International ed. in English)2021
Cycloparaphenylene-Phenalenyl Radical and Its Dimeric Double Nanohoop*.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Article
- π-Radical Cascades to Peri-Fused Triangulene Dimers.Angewandte Chemie (International ed. in English) · 2026Article
- Benzo[cd]azulenyl: A Structural Isomer of Phenalenyl-Synthesis and Properties of Its Tri-tert-butyl-substituted Derivative and Formation of a Thermal- and Photoresponsive σ-Dimer.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Double encapsulation of COrganic chemistry frontiers : an international journal of organic chemistry · 2026Article
- Carbenes Embedded in Cyclic Paraphenylenes: Detection, Ground-State Spin Multiplicity, and Möbius Aromaticity.Journal of the American Chemical Society · 2026Article
- Exploring the World of Double Nanohoops.Angewandte Chemie (International ed. in English) · 2026Review
- Synthesis of Enantiopure [3]Cyclorubicenes.Angewandte Chemie (International ed. in English) · 2026Article
- Size and Geometry Impact the Chiroptical Properties of Double Nanohoops.Journal of the American Chemical Society · 2025Article
- COLUMBUS─An Efficient and General Program Package for Ground and Excited State Computations Including Spin-Orbit Couplings and Dynamics.The journal of physical chemistry. A · 2025Article
- Crown ether-cycloparaphenylene hybrid multimacrocycles: insights into supramolecular gas sensing and biological potential.Chemical science · 2025Article
- Enantio- and Diastereoselective Synthesis and Spiral-Stair-Like Single Helix Assembly of Figure-Eight Cyclophenylenes.Angewandte Chemie (International ed. in English) · 2025Article
- Photoinduced Electron Transfer in Inclusion Complexes of Carbon Nanohoops.Accounts of chemical research · 2024Article
- Bismacrocycle: Structures and Applications.Molecules (Basel, Switzerland) · 2023Review
- Observation of the Magnetic Ground State of the Two Smallest Triangular Nanographenes.JACS Au · 2023Article
- Merging a Negatively Curved Nanographene and a Carbon Nanoring.Precision chemistry · 2023Article
- Nonacethrene Unchained: A Cascade to Chiral Contorted Conjugated Hydrocarbon with Two spJACS Au · 2022Article
- An unexpected dual-emissive luminogen with tunable aggregation-induced emission and enhanced chiroptical property.Nature communications · 2022Article
- Fullerene Wires Assembled Inside Carbon Nanohoops.ChemPlusChem · 2022Review
- Cycloparaphenylene Double Nanohoop: Structure, Lamellar Packing, and Encapsulation of COrganic letters · 2021Article
- Cycloparaphenylene-Phenalenyl Radical and Its Dimeric Double Nanohoop*.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
The first example of a neutral spin-delocalized carbon-nanoring radical was achieved by integration of the open-shell phenalenyl unit into cycloparaphenylene (CPP). Spin distribution in this hydrocarbon is localized primarily on the phenalenyl segment and partially on the CPP segment as a consequence of steric and electronic effects. The resulting geometry is reminiscent of a diamond ring, with pseudo-perpendicular arrangement of the radial and the planar π-surface. The phenylene rings attached directly to the phenalenyl unit give rise to a steric effect that governs a highly selective dimerization pathway, yielding a giant double nanohoop. Its π-framework made of 158 sp
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.