ArticleNature communications2021
Probing intramolecular vibronic coupling through vibronic-state imaging.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
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Who cites it
22 citing papers in PubMed.
- Visualizing excitonic states in constructed cyclic molecular architectures by tip-enhanced photoluminescence.Nature communications · 2026Article
- Molecular jackhammers induce intracellular calcium release and skeletal muscle contraction by vibronic-driven action.Chemical science · 2026Article
- Electronically Forbidden Raman Pathways Create a New Contrast Mechanism in Single-Molecule TERS.Nano letters · 2026Article
- "Direct" measurement of delocalized molecular excitonic wave functions through excitonic and vibronic photon imaging.Science advances · 2026Article
- Single-Molecule Phosphorescence and Intersystem Crossing in a Coupled Exciton Plasmon System.ACS nano · 2025Article
- Charge Transfer of Metal Porphyrins on a NaCl Thin Film Observed by Scanning Tunneling Microscopy in the Transport Gap.ACS nano · 2025Article
- Plasmon hybridization model in molecules: molecular jackhammers.Chemical science · 2025Article
- Controlled single-electron transfer enables time-resolved excited-state spectroscopy of individual molecules.Nature nanotechnology · 2025Article
- Vibronic Effects Analysis of the Substituent Effect on the Spectral Properties of the EMI and CPL of Three [7]Helicene Derivatives.Molecules (Basel, Switzerland) · 2024Article
- Divergent Syntheses of Near-Infrared Light-Activated Molecular Jackhammers for Cancer Cell Eradication.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Ultrafast Time-Domain Spectroscopy Reveals Coherent Vibronic Couplings upon Electronic Excitation in Crystalline Organic Thin Films.The journal of physical chemistry letters · 2024Article
- Charge-transfer dipole low-frequency vibronic excitation at single-molecular scale.Science advances · 2024Article
- Exploring the Role of Excited States' Degeneracy on Vibronic Coupling with Atomic-Scale Optics.ACS nano · 2024Article
- Theoretical study of the photoisomerization of 1,2-bispyrazinyl-ethylene and the halogen ion salts of 1-Pyrazinyl-2-(4'-methylpyrazinyl)ethylene.Journal of molecular modeling · 2024Article
- Molecular jackhammers eradicate cancer cells by vibronic-driven action.Nature chemistry · 2024Article
- Anomalously bright single-molecule upconversion electroluminescence.Nature communications · 2024Article
- Optical Imaging of a Single Molecule with Subnanometer Resolution by Photoinduced Force Microscopy.ACS nano · 2024Article
- Hot luminescence from single-molecule chromophores electrically and mechanically self-decoupled by tripodal scaffolds.Nature communications · 2023Article
- Strong signature of electron-vibration coupling in molecules on Ag(111) triggered by tip-gated discharging.Nature communications · 2023Article
- Toward a BT.2020 green emitter through a combined multiple resonance effect and multi-lock strategy.Nature communications · 2022Article
Corrections and comments
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Authors and funding
11 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Vibronic coupling is a central issue in molecular spectroscopy. Here we investigate vibronic coupling within a single pentacene molecule in real space by imaging the spatial distribution of single-molecule electroluminescence via highly localized excitation of tunneling electrons in a controlled plasmonic junction. The observed two-spot orientation for certain vibronic-state imaging is found to be evidently different from the purely electronic 0-0 transition, rotated by 90°, which reflects the change in the transition dipole orientation from along the molecular short axis to the long axis. Such a change reveals the occurrence of strong vibronic coupling associated with a large Herzberg-Teller contribution, going beyond the conventional Franck-Condon picture. The emergence of large vibration-induced transition charges oscillating along the long axis is found to originate from the strong dynamic perturbation of the anti-symmetric vibration on those carbon atoms with large transition density populations during electronic transitions.
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Registered trials
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