ReviewChemical communications (Cambridge, England)2021
Tuning metal-metal interactions for cooperative small molecule activation.
Review in Chemical communications (Cambridge, England), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
28 citing papers in PubMed.
- Defined Dinuclear Nickel Sites on Mesoporous Silica Translate Molecular Surface Mimics to Heterogeneous Catalysis.Angewandte Chemie (International ed. in English) · 2026Article
- Divergent construction of Ni and Fe-Al-H assemblies.Chemical communications (Cambridge, England) · 2026Article
- A heterobimetallic journey from ambiphilic Ti phosphide to nucleophilic Ti/Ir phosphinidene.Chemical science · 2026Article
- Protonation-Induced Electron Density Redistribution Facilitates Aggregation in PNNP Dicopper Hydride Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Long-range metal-metal cooperative nitrile activation in 1,8-diazaanthracene-supported dicopper complexes.Chemical communications (Cambridge, England) · 2026Article
- Entropy-Driven Ligand Exchange in a Rotationally Flexible Dinuclear Fe(II)-Fe(II) Complex.Inorganic chemistry · 2026Article
- Leveraging Chelating Amido Ligands to Support Metal-Metal Bonding in Dinuclear Cr(II) Complexes.Inorganic chemistry · 2026Article
- Snapshots of Cooperative Trimetallic Alkene Hydrogenation.Journal of the American Chemical Society · 2025Article
- Synthesis and Characterization of Bimetallic Copper(I) Complexes Supported by a Hexadentate Naphthyridine-Based Macrocycle Ligand.Inorganic chemistry · 2025Article
- Alkyne dimerization-hydroarylation to form pentasubstituted 1,3-dienes via binuclear nickel catalysis.Nature communications · 2025Article
- Selective arrangement of three types of calcium-terbium tetranuclear cores by a thiacalixarene ligand using thermodynamic and kinetic strategies.RSC advances · 2025Article
- Chloride, Alkoxide, or Silicon: The Bridging Ligand Dictates the Spin State in Dicobalt Expanded Pincer Complexes.Organometallics · 2025Article
- Hydrogenation Reactions with Heterobimetallic Complexes.Angewandte Chemie (International ed. in English) · 2024Review
- Controlling the Size of Molecular Copper Clusters Supported by a Multinucleating Macrocycle.Inorganic chemistry · 2024Article
- Reactivity Profile of a Formally Dicobalt(0) Complex Bound by a Redox-Active Macrocycle.Organometallics · 2024Article
- Article
- Influence of Metal Identity and Complex Nuclearity in Kumada Cross-Coupling Polymerizations with a Pyridine Diimine-Based Ligand Scaffold.ACS polymers Au · 2023Article
- Cooperative dihydrogen activation with unsupported uranium-metal bonds and characterization of a terminal U(iv) hydride.Chemical science · 2023Article
- Binuclear Complexes Supported by a Tetrapyridyl Ligand with a Bending Anthraquinodimethane Linker.ACS organic & inorganic Au · 2023Article
- Added Complexity!-Mechanistic Aspects of Heterobimetallic Complexes for Application in Homogeneous Catalysis.Molecules (Basel, Switzerland) · 2023Review
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Cluster complexes have attracted interest for decades due to their promise of drawing analogies to metallic surfaces and metalloenzyme active sites, but only recently have chemists started to develop ligand scaffolds that are specifically designed to support multinuclear transition metal cores. Such ligands not only hold multiple metal centers in close proximity but also allow for fine-tuning of their electronic structures and surrounding steric environments. This Feature Article highlights ligand designs that allow for cooperative small molecule activation at cluster complexes, with a particular focus on complexes that contain metal-metal bonds. Two useful ligand-design elements have emerged from this work: a degree of geometric flexibility, which allows for novel small molecule activation modes, and the use of redox-active ligands to provide electronic flexibility to the cluster core. The authors have incorporated these factors into a unique class of dinucleating macrocycles (
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.