ArticleAngewandte Chemie (International ed. in English)2021
Titanium-Catalyzed Intermolecular Hydroaminoalkylation of Alkenes with Tertiary Amines.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Anti-Markovnikov Hydroamination of Vinylpyridines via a Novel Photocatalytic Strategy.Molecules (Basel, Switzerland) · 2026Article
- The Synthesis of Tertiary Alkylamines from Alkyl-Substituted Alkenes Using Amine Umpolung Strategy.Journal of the American Chemical Society · 2026Article
- Titanium-Catalyzed Intermolecular Hydrothiomethylation of Alkenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Role of Spectator Species for Amine-Surface Chemistry: Reactions of Amines and Alkenes on Pt(111).Journal of the American Chemical Society · 2025Article
- Tantalum ureate complexes for photocatalytic hydroaminoalkylation.Chemical science · 2023Article
- Regio-, Diastereo-, and Enantioselective Decarboxylative Hydroaminoalkylation of Dienol Ethers Enabled by Dual Palladium/Photoredox Catalysis.Angewandte Chemie (International ed. in English) · 2022Article
- Stereoselective Synthesis of Tertiary Allylic Amines by Titanium-Catalyzed Hydroaminoalkylation of Alkynes with Tertiary Amines.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Photocatalytic Hydroaminoalkylation of Styrenes with Unprotected Primary Alkylamines.Journal of the American Chemical Society · 2021Article
- Titanium-Catalyzed Intermolecular Hydroaminoalkylation of Alkenes with Tertiary Amines.Angewandte Chemie (International ed. in English) · 2021Article
- C-H Bond Functionalization of Amines: A Graphical Overview of Diverse Methods.SynOpen (2017) · 2021Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
The first cationic titanium catalyst system for the intermolecular hydroaminoalkylation of alkenes with various tertiary alkylamines is presented. Corresponding reactions which involve the addition of the α-C-H bond of a tertiary amine across the C-C double bond of an alkene take place at temperatures close to room temperature with excellent regioselectivity to deliver the branched products exclusively. Interestingly, for selected amines, α-C-H bond activation occurs not only at N-methyl but also at N-methylene groups.
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Registered trials
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