ArticleAngewandte Chemie (International ed. in English)2021
Stimulation of Redox-Induced Electron Transfer by Interligand Hydrogen Bonding in a Cobalt Complex with Redox-Active Guanidine Ligand.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
9 citing papers in PubMed, 36 citations in OpenAlex.
- Modulating the Electron Mediators for Spatially Separated HAngewandte Chemie (International ed. in English) · 2026Article
- Triggering and Preventing Cyclization of o-Amino-Guanidinobenzenes to 2-Amino-Benzimidazoles.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Bistability in Palladium Complexes with Two Different Redox-Active Ligands of Orthogonal Charge Regimes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Steric Restraints in Redox-Active Guanidine Ligands and Their Impact on Coordination Chemistry.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Fine Tuning of the Redox-Active Diguanidine Ligand in Cationic Cobalt Complexes for Electronic Structure Control.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Interplay and Competition Between Two Different Types of Redox-Active Ligands in Cobalt Complexes: How to Allocate the Electrons?Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- A Copper(I) Complex with Two Unpaired Electrons, Synthesised by Oxidation of a Copper(II) Complex with Two Redox-Active Ligands.Angewandte Chemie (International ed. in English) · 2021Article
- Switching from Metal- to Ligand-Based Oxidation in Cobalt Complexes with Redox-Active Bisguanidine Ligands.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Stimulation of Redox-Induced Electron Transfer by Interligand Hydrogen Bonding in a Cobalt Complex with Redox-Active Guanidine Ligand.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Octahedrally coordinated cobalt(II) complexes with a redox-active bisguanidine ligand and acac co-ligands were synthesized and their redox chemistry analysed in detail. The N-H functions in a bisguanidine ligand with partially alkylated guanidino groups form N-H⋅⋅⋅O hydrogen bonds with the acac co-ligands, thereby massively influencing the redox chemistry. For all complexes, the first one-electron oxidation is metal-centred, leading to Co
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.