ArticleNature communications2021
Highly active alkyne metathesis catalysts operating under open air condition.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed, 48 citations in OpenAlex.
- Reactivity of a dAngewandte Chemie (International ed. in English) · 2026Article
- Supramolecular protection of isocyanates from water by encapsulation within hydrophobic crystalline pillar[n]arene macrocycles.Nature communications · 2026Article
- Synthesis of Conjugated Linear and Cyclic Polyynes by Selective Alkyne Metathesis.Angewandte Chemie (International ed. in English) · 2026Article
- Ring-Opening Alkyne Metathesis Polymerization Catalyzed by a Bench-Stable Rhenium Complex.Journal of the American Chemical Society · 2026Article
- Rhenium Alkyne Catalysis: Sterics Control the Reactivity.Inorganic chemistry · 2024Article
- From the Glovebox to the Benchtop: Air-Stable High Performance Molybdenum Alkylidyne Catalysts for Alkyne Metathesis.Journal of the American Chemical Society · 2023Article
- Canopy Catalysts for Alkyne Metathesis: Investigations into a Bimolecular Decomposition Pathway and the Stability of the Podand Cap.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- The Ascent of Alkyne Metathesis to Strategy-Level Status.Journal of the American Chemical Society · 2021Article
- By-design molecular architecturesChemical science · 2021Review
- Impact of Ligands and Metals on the Formation of Metallacyclic Intermediates and a Nontraditional Mechanism for Group VI Alkyne Metathesis Catalysts.Journal of the American Chemical Society · 2021Article
Corrections and comments
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Authors and funding
9 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Alkyne metathesis represents a rapidly emerging synthetic method that has shown great potential in small molecule and polymer synthesis. However, its practical use has been impeded by the limited availability of user-friendly catalysts and their generally high moisture/air sensitivity. Herein, we report an alkyne metathesis catalyst system that can operate under open-air conditions with a broad substrate scope and excellent yields. These catalysts are composed of simple multidentate tris(2-hydroxyphenyl)methane ligands, which can be easily prepared in multi-gram scale. The catalyst substituted with electron withdrawing cyano groups exhibits the highest activity at room temperature with excellent functional group tolerance (-OH, -CHO, -NO
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.