ArticleACS nano2021
Solvent-Resistant Lignin-Epoxy Hybrid Nanoparticles for Covalent Surface Modification and High-Strength Particulate Adhesives.
Article in ACS nano, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Aqueous lignin adhesive for high-performance wood bonding.Science advances · 2026Article
- Lignin-Based Adhesives for Various Packaging Applications.Polymers · 2026Review
- Advanced Characterization of Lignin Nanoparticles by Asymmetric Flow-Field Flow Fractionation.ChemSusChem · 2025Article
- Lignin Ultrafiltration Fractionation and Self-Assembly to Monodisperse Nanoparticles for Photonic Materials.ACS omega · 2025Article
- Overcoming Challenges of Lignin Nanoparticles: Expanding Opportunities for Scalable and Multifunctional Nanomaterials.Accounts of chemical research · 2024Article
- Bridging Smart Nanosystems with Clinically Relevant Models and Advanced Imaging for Precision Drug Delivery.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Review
- Urushi as a Green Component for Thermally Curable Colloidal Lignin Particles and Hydrophobic Coatings.ACS macro letters · 2023Article
- Functional surfaces, films, and coatings with lignin - a critical review.RSC advances · 2023Review
- Biobased Nanomaterials─The Role of Interfacial Interactions for Advanced Materials.Chemical reviews · 2023Review
- Stabilized Lignin Nanoparticles for Versatile Hybrid and Functional Nanomaterials.Biomacromolecules · 2022Article
- Bio-macromolecular design roadmap towards tough bioadhesives.Chemical Society reviews · 2022Review
- Experimental and Simulation Study of the Solvent Effects on the Intrinsic Properties of Spherical Lignin Nanoparticles.The journal of physical chemistry. B · 2021Article
- Multifunctional lignin-based nanocomposites and nanohybrids.Green chemistry : an international journal and green chemistry resource : GC · 2021Review
- Chitin-amyloid synergism and their use as sustainable structural adhesives.Journal of materials chemistry. A · 2021Article
- Unravelling the Hydration Barrier of Lignin Oleate Nanoparticles for Acid- and Base-Catalyzed Functionalization in Dispersion State.Angewandte Chemie (International ed. in English) · 2021Article
- Towards sustainable production and utilization of plant-biomass-based nanomaterials: a review and analysis of recent developments.Biotechnology for biofuels · 2021Review
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Fabrication of spherical lignin nanoparticles (LNPs) is opening more application opportunities for lignin. However, dissolution of LNPs at a strongly alkaline pH or in common organic solvent systems has prevented their surface functionalization in a dispersion state as well as processing and applications that require maintaining the particle morphology under harsh conditions. Here, we report a simple method to stabilize LNPs through intraparticle cross-linking. Bisphenol A diglycidyl ether (BADGE), a cross-linker that, like lignin, contains substituted benzene rings, is coprecipitated with softwood Kraft lignin to form hybrid LNPs (hy-LNPs). The hy-LNPs with a BADGE content ≤20 wt % could be intraparticle cross-linked in the dispersion state without altering their colloidal stability. Atomic force microscopy and quartz crystal microbalance with dissipation monitoring were used to show that the internally cross-linked particles were resistant to dissolution under strongly alkaline conditions and in acetone-water binary solvent that dissolved unmodified LNPs entirely. We further demonstrated covalent surface functionalization of the internally cross-linked particles at pH 12 through an epoxy ring-opening reaction to obtain particles with pH-switchable surface charge. Moreover, the hy-LNPs with BADGE content ≥30% allowed both inter- and intraparticle cross-linking at >150 °C, which enabled their application as waterborne wood adhesives with competitive dry/wet adhesive strength (5.4/3.5 MPa).
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