Evidence map›Paper›PMID 33589783›Full record

ArticleNature chemistry2021

Dipolar order in an amphidynamic crystalline metal-organic framework through reorienting linkers.

Y-S Su, E S Lamb, I Liepuoniute, A Chronister, A L Stanton, P Guzman, S Pérez-Estrada, T Y Chang, K N Houk, M A Garcia-Garibay and 1 more

Abstract read
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In one paragraph

Article in Nature chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.

0numbers the graph read from it
0cells of the map it votes in
15citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

15 citing papers in PubMed.

  1. Engineering Ultrafast Molecular Rotors via Chalcogen bonds.Journal of the American Chemical Society · 2026
    Article
  2. Article
  3. Article
  4. Review
  5. Article
  6. Article
  7. Article
  8. Breaking the photoswitch speed limit.Nature communications · 2023
    Article
  9. Article
  10. Article
  11. Functional dynamics in framework materials.Communications chemistry · 2023
    Review
  12. Review
  13. Review
  14. Article
  15. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Y-S Su *Department of Physics and Astronomy, University of California, Los Angeles, Los Angeles, CA, USA. jim770307@gmail.com.ORCID http://orcid.org/0000-0002-4790-9153
E S Lamb *Department of Physics and Astronomy, University of California, Los Angeles, Los Angeles, CA, USA.
I Liepuoniute *Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA, USA. ieva@ucla.edu.ORCID http://orcid.org/0000-0003-2965-8642
A ChronisterDepartment of Physics and Astronomy, University of California, Los Angeles, Los Angeles, CA, USA.
A L StantonDepartment of Physics and Astronomy, University of California, Los Angeles, Los Angeles, CA, USA.
P GuzmanDepartment of Physics and Astronomy, University of California, Los Angeles, Los Angeles, CA, USA.
S Pérez-EstradaDepartment of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA, USA.
T Y ChangDepartment of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA, USA.
K N HoukDepartment of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA, USA.ORCID http://orcid.org/0000-0002-8387-5261
M A Garcia-GaribayDepartment of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA, USA. mgg@chem.ucla.edu.ORCID http://orcid.org/0000-0002-6268-1943
S E BrownDepartment of Physics and Astronomy, University of California, Los Angeles, Los Angeles, CA, USA. brown@physic.ucla.edu.ORCID http://orcid.org/0000-0003-0086-7723

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Amphidynamic crystals, which possess crystallinity and support dynamic behaviours, are very well suited to the exploration of emergent phenomena that result from the coupling on the dynamic moieties. Here, dipolar rotors have been embedded in a crystalline metal-organic framework. The material consists of Zn(II) nodes and two types of ditopic bicyclo[2.2.2]octane-based linkers-one that coordinates to the Zn clusters through two 1,4-aza moieties, and a difluoro-functionalized derivative (the dipolar rotor) that coordinates through linked 1,4-dicarboxylate groups instead. Upon cooling, these linkers collectively order as a result of correlated dipole-dipole interactions. Variable-temperature, frequency-dependent dielectric measurements revealed a transition temperature T

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.