ArticleNature chemistry2021
Dipolar order in an amphidynamic crystalline metal-organic framework through reorienting linkers.
Article in Nature chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Engineering Ultrafast Molecular Rotors via Chalcogen bonds.Journal of the American Chemical Society · 2026Article
- Turn-on luminescence from molecular rotor realignment in metal-organic framework thin films.Nature communications · 2026Article
- Responsive interlayer spacing in staggered metal-organic framework nanosheet membranes.Nature communications · 2026Article
- Design of Molecular Crystals toward Crystalline Molecular Machines: Rotors, Gears, and Motors.ACS nanoscience Au · 2025Review
- sln-Topological Covalent Organic Frameworks with Shape Dimorphism and Dipolar Rotors.Journal of the American Chemical Society · 2025Article
- Rational Design of Electric Field-Responsive Building Blocks for All-Organic 2D Magnetoelectric Materials.Journal of the American Chemical Society · 2025Article
- Space-confined charge transfer turns on multicolor emission in metal-organic frameworks via pressure treatment.Nature communications · 2025Article
- Breaking the photoswitch speed limit.Nature communications · 2023Article
- Intrinsic room-temperature ferromagnetism in a two-dimensional semiconducting metal-organic framework.Nature communications · 2023Article
- Benzothiadiazole-based rotation and possible antipolar order in carboxylate-based metal-organic frameworks.Communications chemistry · 2023Article
- Functional dynamics in framework materials.Communications chemistry · 2023Review
- Review
- Controlling dynamics in extended molecular frameworks.Nature reviews. Chemistry · 2022Review
- Microporous hierarchically Zn-MOF as an efficient catalyst for the Hantzsch synthesis of polyhydroquinolines.Scientific reports · 2022Article
- Cascade Dynamics of Multiple Molecular Rotors in a MOF: Benchmark Mobility at a Few Kelvins and Dynamics Control by COJournal of the American Chemical Society · 2021Article
Corrections and comments
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Authors and funding
11 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Amphidynamic crystals, which possess crystallinity and support dynamic behaviours, are very well suited to the exploration of emergent phenomena that result from the coupling on the dynamic moieties. Here, dipolar rotors have been embedded in a crystalline metal-organic framework. The material consists of Zn(II) nodes and two types of ditopic bicyclo[2.2.2]octane-based linkers-one that coordinates to the Zn clusters through two 1,4-aza moieties, and a difluoro-functionalized derivative (the dipolar rotor) that coordinates through linked 1,4-dicarboxylate groups instead. Upon cooling, these linkers collectively order as a result of correlated dipole-dipole interactions. Variable-temperature, frequency-dependent dielectric measurements revealed a transition temperature T
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.