ArticleJournal of the American Chemical Society2021
Electronic Relaxation Pathways in Heavy-Atom-Free Photosensitizers Absorbing Near-Infrared Radiation and Exhibiting High Yields of Singlet Oxygen Generation.
Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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Who cites it
19 citing papers in PubMed.
- Double Thionation of 4-Dimethylaminophthalimide Leads to the Development of a Highly Effective Photosensitizer.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Near-Infrared-Responsive Catalysts for Gas-Solid Phase Photocatalytic COChemistry (Weinheim an der Bergstrasse, Germany) · 2026Review
- Development of a Nucleoside Photosensitizer Efficiently Activated by One- or Two-Photon Absorption in the Optical Therapeutic Window.Journal of the American Chemical Society · 2026Article
- Crystalline nanofiber photosensitizers with twisted dual-acceptors: high light harvesting and singlet oxygen quantum yield.National science review · 2026Article
- Molecular design and excited state dynamics regulation in phototheranostics.Biophysics reports · 2025Article
- The controllable of BODIPY dimers without installing blocking groups as both fluorescence and singlet oxygen generators.Smart molecules : open access · 2025Article
- Thio and Seleno Derivatives of Angelicin as Efficient Triplet Harvesting Photosensitizers: Implications in Photodynamic Therapy.Chemphyschem : a European journal of chemical physics and physical chemistry · 2024Article
- Molecular Engineering of a Tumor-Targeting Thione-Derived Diketopyrrolopyrrole Photosensitizer to Attain NIR Excitation Over 850 nm for Efficient Dual Phototherapy.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Electronic relaxation pathways in thio-acridone and thio-coumarin: two heavy-atom-free photosensitizers absorbing visible light.Physical chemistry chemical physics : PCCP · 2024Article
- Synthesis of Thionated Perylenediimides: State of the Art and First Investigations of an Alternative to Lawesson's Reagent.Molecules (Basel, Switzerland) · 2024Review
- Emerging potential approaches in alkaline phosphatase (ALP) activatable cancer theranostics.RSC medicinal chemistry · 2024Review
- Conditionally Activatable Pyroptosis-Inducing Agents for Cancer Therapy.Small science · 2024Article
- Thieno[3,4-Chemical science · 2023Article
- Visible light-activated prodrug system with a novel heavy-atom-free photosensitizer.Bioorganic & medicinal chemistry letters · 2023Article
- Unraveling an Ultrafast Electron Transport Mechanism in a Photocatalytic "Micromachine" for Their Potential Light Harvesting Applications.Micromachines · 2023Article
- Sulphur- and Selenium-for-Oxygen Replacement as a Strategy to Obtain Dual Type I/Type II Photosensitizers for Photodynamic Therapy.Molecules (Basel, Switzerland) · 2023Article
- Site-selected thionated benzothioxanthene chromophores as heavy-atom-free small-molecule photosensitizers for photodynamic therapy.Communications chemistry · 2022Article
- Chalcogen Effects in the Photophysical Properties of Dimethylamino-1,8-naphthalimide Dyes Revealed by DFT Investigation.The journal of physical chemistry. A · 2022Article
- Bridging D-A type photosensitizers with the azo group to boost intersystem crossing for efficient photodynamic therapy.Chemical science · 2022Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Heavy-atom-free photosensitizers (HAF-PSs) based on thionation of carbonyl groups of readily accessible organic compounds are rapidly emerging as a versatile class of molecules. However, their photochemical properties and electronic relaxation mechanisms are currently unknown. Investigating the excited-state dynamics is essential to understand their benefits and limitations and to develop photosensitizers with improved photochemical properties. Herein, the photochemical and electronic-structure properties of two of the most promising HAF-PSs developed to date are revealed. It is shown that excitation of thio-4-(dimethylamino)naphthalamide and thionated Nile Red with near-infrared radiation leads to the efficient population of the triplet manifold through multiple relaxation pathways in hundreds of femtoseconds. The strong singlet-triplet couplings in this family of photosensitizers should enable a broad range of applications, including in photodynamic therapy, photocatalysis, photovoltaics, organic LEDs, and photon up-conversion.
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