ArticleInorganic chemistry2021
Metrical Oxidation States of 1,4-Diazadiene-Derived Ligands.
Article in Inorganic chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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10 citing papers in PubMed.
- Manganese Complexes Bearing Bulky DAB Ligands as Efficient Catalysts for the Solvent-Free Hydroboration of Ketones.International journal of molecular sciences · 2025Article
- Platform Design Enabling Silver(III) Stabilization ─ The Uprise of AgChemistry (Weinheim an der Bergstrasse, Germany) · 2025Review
- Selective dehydrogenation of ammonia borane to polycondensated BN rings catalysed by ruthenium olefin complexes.Chemical communications (Cambridge, England) · 2024Article
- Computational mechanistic studies of ruthenium catalysed methanol dehydrogenation.Dalton transactions (Cambridge, England : 2003) · 2022Review
- Article
- Valence Tautomerism of p-Block Element Compounds - An Eligible Phenomenon for Main Group Catalysis?European journal of inorganic chemistry · 2022Review
- Di-tert-butyldiphosphatetrahedrane as a Source of 1,2-Diphosphacyclobutadiene Ligands.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Aminotroponiminates: Impact of the NOChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Controlling Radical-Type Single-Electron Elementary Steps in Catalysis with Redox-Active Ligands and Substrates.JACS Au · 2021Review
- Switching from Metal- to Ligand-Based Oxidation in Cobalt Complexes with Redox-Active Bisguanidine Ligands.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
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5 authors.
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Abstract
The conventional method of assigning formal oxidation states (FOSs) to metals and ligands is an important tool for understanding and predicting the chemical reactivity, in particular, in catalysis research. For complexes containing redox-noninnocent ligands, the oxidation state of the ligand can be ambiguous (i.e., their spectroscopic oxidation state can differ from the FOS) and thus frustrates the assignment of the oxidation state of the metal. A quantitative correlation between the empirical metric data of redox-active ligands and their oxidation states using a metrical oxidation state (MOS) model has been developed for catecholate- and amidophenoxide-derived ligands by Brown. In the present work, we present a MOS model for 1,4-diazabutadiene (DAD
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