Evidence map›Paper›PMID 33578771›Full record

ArticlePolymers2021

Water Vapor Sorption and Diffusivity in Bio-Based Poly(Ethylene Vanillate)-PEV.

Greta Giacobazzi, Claudio Gioia, Micaela Vannini, Paola Marchese, Valérie Guillard, Hélène Angellier-Coussy, Annamaria Celli

Abstract read
In one paragraph

Article in Polymers, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Greta GiacobazziDepartment of Civil, Chemical, Environmental and Materials Engineering, Alma Mater Studiorum/University of Bologna, Via Terracini 28, 40131 Bologna, Italy.
Claudio GioiaDepartment of Civil, Chemical, Environmental and Materials Engineering, Alma Mater Studiorum/University of Bologna, Via Terracini 28, 40131 Bologna, Italy.
Micaela VanniniDepartment of Civil, Chemical, Environmental and Materials Engineering, Alma Mater Studiorum/University of Bologna, Via Terracini 28, 40131 Bologna, Italy.ORCID 0000-0001-7599-3797
Paola MarcheseDepartment of Civil, Chemical, Environmental and Materials Engineering, Alma Mater Studiorum/University of Bologna, Via Terracini 28, 40131 Bologna, Italy.ORCID 0000-0002-6260-4163
Valérie GuillardAgropolymers Engineering & Emerging Technology, University of Montpellier-INRAE- SupAgro, 2 Place Pierre Viala, Bât 31, 34060 Montpellier, France.ORCID 0000-0002-7117-1988
Hélène Angellier-CoussyAgropolymers Engineering & Emerging Technology, University of Montpellier-INRAE- SupAgro, 2 Place Pierre Viala, Bât 31, 34060 Montpellier, France.ORCID 0000-0001-5482-7095
Annamaria CelliDepartment of Civil, Chemical, Environmental and Materials Engineering, Alma Mater Studiorum/University of Bologna, Via Terracini 28, 40131 Bologna, Italy.

Funding

European Commission 688338
6 · The paper itself

Abstract

The dynamic and equilibrium water vapor sorption properties of amorphous and highly crystalline poly(ethylene vanillate) (PEV) films were determined via gravimetric analysis, at 20 °C, over a wide range of relative humidity (0-95% RH). At low RH%, the dynamic of the sorption process obeys Fick's law while at higher relative humidity it is characterized by a drift ascribable to non-Fickian relaxations. The non-Fickian relaxations, which are responsible for the incorporation of additional water, are correlated with the upturn of the sorption isotherms and simultaneously the hysteresis recorded between sorption and desorption cycles. The sorption isotherms of amorphous and highly crystalline PEV are arranged in the same concentration range of that of PET proving the similarity of the two polyesters. Water diffusion coefficients, whose determination from individual kinetic sorption/desorption curves required treatment with the Barens-Hopfenberg model, were demonstrated to be ≈ 10× higher for amorphous PEV compared to amorphous PET. Such a difference originates from the enhanced segmental flexibility of PEV chains.

Indexed as

diffusivitypoly(ethylene vanillate)water sorptionwater transport

Identifiers

PMID33578771
PMCPMC7916482

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.